POTASSIUM CARBONATE, SESQUIHYDRATE

Modify Date: 2024-01-11 13:00:38

POTASSIUM CARBONATE, SESQUIHYDRATE Structure
POTASSIUM CARBONATE, SESQUIHYDRATE structure
Common Name POTASSIUM CARBONATE, SESQUIHYDRATE
CAS Number 6381-79-9 Molecular Weight 330.457
Density 2.043 Boiling Point 333.6ºC at 760 mmHg
Molecular Formula C2H6K4O9 Melting Point 891ºC
MSDS Chinese USA Flash Point 169.8ºC
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name potassium carbonate, sesquihydrate
Synonym More Synonyms

 Chemical & Physical Properties

Density 2.043
Boiling Point 333.6ºC at 760 mmHg
Melting Point 891ºC
Molecular Formula C2H6K4O9
Molecular Weight 330.457
Flash Point 169.8ºC
Exact Mass 329.856018
PSA 154.07000
Appearance of Characters Solid | White
Storage condition Store at +15°C to +25°C.
Water Solubility 1300g/l | Soluble in water. Practically insoluble in alcohol

 MSDS


Section 1. Chemical Product and Company Identification
Potassium carbonate Sesquihydrate
Common Name/
Trade Name
Manufacturer
Commercial Name(s)
Synonym
Chemical Name
Chemical Family
Potassium carbonate Sesquihydrate
CARCINOGENIC EFFECTS: Not available.
Potential Chronic Health
EffectsMUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
The substance is toxic to mucous membranes.
The substance may be toxic to skin, eyes.
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure of the
eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction,
or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.

Section 4. First Aid Measures
Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin ContactIn case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before
reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Serious Skin ContactWash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
InhalationIf inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention immediately.
Serious InhalationNot available.
IngestionDo NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Serious IngestionNot available.

Section 5. Fire and Explosion Data
Flammability of the Product Non-flammable.
Auto-Ignition Temperature Not applicable.
Flash PointsNot applicable.
Flammable LimitsNot applicable.
Products of CombustionNot available.
Fire Hazards in Presence of Not applicable.
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
of Various SubstancesRisks of explosion of the product in presence of static discharge: Not available.
Fire Fighting MediaNot applicable.
and Instructions
Special Remarks onNot available.
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
Potassium carbonate Sesquihydrate

Section 6. Accidental Release Measures
Small SpillUse appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize
the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated
surface and dispose of according to local and regional authority requirements.
Large SpillCorrosive solid.
Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
disposal. Neutralize the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7. Handling and Storage
PrecautionsKeep container dry. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient
ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the
container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents,
metals, acids.
StorageKeep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).

Section 8. Exposure Controls/Personal Protection
Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal ProtectionSplash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or
equivalent. Gloves.
Personal Protection in Case of Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus
a Large Spillshould be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a
specialist BEFORE handling this product.
Exposure LimitsNot available.

Section 9. Physical and Chemical Properties
Physical state and appearance Solid. (Powdered solid. Deliquescent solid.)OdorOdorless.
TasteNot available.
165.23 g/mole
Molecular Weight
ColorWhite.
pH (1% soln/water)11.6 [Basic.]
Boiling PointDecomposes.
Melting Point891.11°C (1636°F)
Critical TemperatureNot available.
Specific GravityNot available.
Not applicable.
Vapor Pressure
Vapor DensityNot available.
VolatilityNot available.
Odor ThresholdNot available.
Water/Oil Dist. Coeff.Not available.
Not available.
Ionicity (in Water)
Dispersion PropertiesSee solubility in water.
Soluble in cold water.
Solubility
Potassium carbonate Sesquihydrate

Section 10. Stability and Reactivity Data
The product is stable.
Stability
Instability TemperatureNot available.
Dust generation, moist air, water, incompatible materials.
Conditions of Instability
Reactive with oxidizing agents, metals, acids.
Incompatibility with various
Slightly reactive to reactive with moisture.
substances
CorrosivityNon-corrosive in presence of glass.
Special Remarks onReacts with water to evolve heat.
ReactivityWhen it contains the full amount of water it is not hygroscopic.
Incompatible with KCO, chlorine trifluoride, calcium oxide, and magnesium
Not available.
Special Remarks on
Corrosivity
PolymerizationWill not occur.

Section 11. Toxicological Information
Routes of EntryEye contact. Inhalation. Ingestion.
Toxicity to AnimalsAcute oral toxicity (LD50): 1870 mg/kg [Rat ].
Chronic Effects on HumansCauses damage to the following organs: mucous membranes.
May cause damage to the following organs: skin, eyes.
Other Toxic Effects on
Extremely hazardous in case of skin contact (corrosive), of inhalation (lung corrosive).
HumansHazardous in case of skin contact (irritant), of ingestion, .
Slightly hazardous in case of eye contact (corrosive).
Special Remarks onNot available.
Toxicity to Animals
Special Remarks onNot available.
Chronic Effects on Humans
Special Remarks on otherAcute Potential Health Effects:
Toxic Effects on HumansSkin: Causes severe skin irritation.
Eyes: It is severely irritating to the eyes and its mucous membranes. It may cause corneal injury. It may cause
burns and loss of vision. It may cause permanent damage. The amount of tissue damage depends on the length
of contact.
Ingestion: It causes gastrointestinal irritation with nausea, vomiting, abdominal pain, swollen glottis, increased
respiration, and possible burns to the lips, tongue, oral mucosa, hypopharynx, stomach, or esophagus. It may
affect the cardiovascular system(circulatory collapse), urinary system, and metabolism.
Inhalation: Causes respiratory tract and mucous membrane irritation. Exposure can cause coughing, chest
pains, and difficulty breathing (dyspnea).

Section 12. Ecological Information
Not available.
Ecotoxicity
BOD5 and CODNot available.
Products of BiodegradationPossibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
The products of degradation are less toxic than the product itself.
Toxicity of the Products
of Biodegradation
Special Remarks on theNot available.
Products of Biodegradation
Potassium carbonate Sesquihydrate

Section 13. Disposal Considerations
Waste DisposalWaste must be disposed of in accordance with federal, state and local environmental
control regulations.

Section 14. Transport Information
DOT ClassificationNot a DOT controlled material (United States).
Not applicable.
Identification
Not applicable.
Special Provisions for
Transport
DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
No products were found.
Federal and State
Regulations
California
Proposition 65
Warnings
Other RegulationsOSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
WHMIS (Canada) Not controlled under WHMIS (Canada).
Other Classifications
DSCL (EEC)R22- Harmful if swallowed.S1/2- Keep locked up and out of the reach of
R36/37/38- Irritating to eyes,children.
respiratory system and skin.S26- In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
S36/37/39- Wear suitable protective clothing,
gloves and eye/face protection.
S45- In case of accident or if you feel unwell,
seek medical advice immediately (show the
label where possible).
S46- If swallowed, seek medical advice
immediately and show this container or label.
Health Hazard
HMIS (U.S.A.)2 National Fire Protection
0 Flammability
0 Association (U.S.A.)
Fire Hazard
2 0 Reactivity
Health
Reactivity
1
Specific hazard
Personal Protection
j
WHMIS (Canada)
(Pictograms)
Potassium carbonate Sesquihydrate
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment
Gloves.
Synthetic apron.
Vapor and dust respirator. Be sure to
use an approved/certified respirator or
equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn
Risk Phrases 22-36/38
Safety Phrases 26
RIDADR NONH for all modes of transport
WGK Germany 1

 Articles2

More Articles
Ab initio thermodynamic study of the CO2 capture properties of potassium carbonate sesquihydrate, K2CO3· 1.5H2O. Duan Y, et al.

J. Phys. Chem. C Nanomater. Interfaces 116(27) , 14461-14470, (2012)

Synthesis of aromatic ketones by Suzuki-Miyaura cross-coupling of acyl chlorides with boronic acids mediated by palladium catalysts deposited over donor-functionalized silica gel. Semler M and Štepnicka P.

Catal. Today 243 , 128-133, (2015)

 Synonyms

EINECS 209-529-3
Potassium carbonate hydrate (4:2:3)
Carbonic acid, potassium salt, hydrate (2:4:3)
tetrapotassium,dicarbonate,trihydrate