Terabutyl titanate

Modify Date: 2024-01-01 19:31:29

Terabutyl titanate Structure
Terabutyl titanate structure
Common Name Terabutyl titanate
CAS Number 5593-70-4 Molecular Weight 388.189
Density 1.00 g/mL at 20 °C(lit.) Boiling Point 206 °C10 mm Hg(lit.)
Molecular Formula C16H36O4Ti2 Melting Point -55°C
MSDS Chinese USA Flash Point 55 °F
Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger

 Names

Name Tetrabutyl titanate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.00 g/mL at 20 °C(lit.)
Boiling Point 206 °C10 mm Hg(lit.)
Melting Point -55°C
Molecular Formula C16H36O4Ti2
Molecular Weight 388.189
Flash Point 55 °F
Exact Mass 388.157257
PSA 36.92000
LogP 5.06960
Index of Refraction n20/D 1.491(lit.)
Stability Stable, but moisture sensitive. Flammable. Incompatible with water, moisture, strong oxidizing agents, strong acids.
Water Solubility RAPIDLY HYDROLIZED

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XR1585000
CHEMICAL NAME :
Titanic acid, tetrabutyl ester
CAS REGISTRY NUMBER :
5593-70-4
LAST UPDATED :
199710
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C16-H36-O4.Ti
MOLECULAR WEIGHT :
340.42
WISWESSER LINE NOTATION :
4O-TI-O4&O4&O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3122 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1263,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01650 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0833 No. of Facilities: 248 (estimated) No. of Industries: 8 No. of Occupations: 30 No. of Employees: 8950 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M0833 No. of Facilities: 1979 (estimated) No. of Industries: 28 No. of Occupations: 32 No. of Employees: 26386 (estimated) No. of Female Employees: 5431 (estimated)

 Safety Information

Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger
Hazard Statements H226-H315-H318-H335-H336
Precautionary Statements P280-P305 + P351 + P338 + P310-P403 + P235
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S16-S26-S39-S24/25
RIDADR UN 1993 3/PG 3
WGK Germany 1
RTECS XR1585000
Packaging Group III
Hazard Class 8
HS Code 29051900

 Synthetic Route

~85%

Terabutyl titanate Structure

Terabutyl titanate

CAS#:5593-70-4

Literature: Journal of applied chemistry of the USSR, , vol. 58, # 8 pt 2 p. 1678 - 1680

~%

Terabutyl titanate Structure

Terabutyl titanate

CAS#:5593-70-4

Literature: J. Coun. scient. ind. Res. AustraliaChem.Abstr., , vol. 21, p. 330 J. Coun. scient. ind. Res. AustraliaChem.Abstr., , p. 1433; 1949 9026 DE720080 , ; DRP/DRBP Org.Chem.

~%

Terabutyl titanate Structure

Terabutyl titanate

CAS#:5593-70-4

Literature: Journal of the American Chemical Society, , vol. 46, p. 258

~%

Terabutyl titanate Structure

Terabutyl titanate

CAS#:5593-70-4

Literature: Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 40, p. 1707 - 1713 Zhurnal Neorganicheskoi Khimii, , vol. 40, p. 1773 - 1780

 Customs

HS Code 29051900

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 Synonyms

Titanium(2+) 1-butanolate (1:2)
BUTYL TITANATE
Tyzor BP
VERTEC(TM) TNBT
tetra-n-butyl titanate
titanium(IV) n-butoxide
TNBT
titaniuM salt
titanium tetra-n-butoxide
titanium(IV) tetra(n-butoxide)
tyzortbt
orgaticsta25
b1(titanate)
EINECS 227-006-8
1-Butanol, titanium(2+) salt (2:1)
MFCD00009433
Ti(OCH2CH2CH2CH3)4
Titanium Butoxide
Terabutyl titanate
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