Chlorotris(trimethylsilyl)silane

Modify Date: 2024-01-10 22:29:34

Chlorotris(trimethylsilyl)silane Structure
Chlorotris(trimethylsilyl)silane structure
Common Name Chlorotris(trimethylsilyl)silane
CAS Number 5565-32-2 Molecular Weight 283.106
Density 0.9±0.1 g/cm3 Boiling Point 225.3±23.0 °C at 760 mmHg
Molecular Formula C9H27ClSi4 Melting Point 50-52ºC(lit.)
MSDS Chinese USA Flash Point 63.3±17.4 °C
Symbol GHS02 GHS07 GHS08
GHS02, GHS07, GHS08
Signal Word Danger

 Names

Name Chlorotris(trimethylsilyl)silane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 225.3±23.0 °C at 760 mmHg
Melting Point 50-52ºC(lit.)
Molecular Formula C9H27ClSi4
Molecular Weight 283.106
Flash Point 63.3±17.4 °C
Exact Mass 282.087830
LogP 6.18
Vapour Pressure 0.1±0.4 mmHg at 25°C
Index of Refraction 1.418

 Safety Information

Symbol GHS02 GHS07 GHS08
GHS02, GHS07, GHS08
Signal Word Danger
Hazard Statements H225-H304-H315-H319-H335 + H336-H361d-H373
Supplemental HS Contact with water liberates toxic gas.
Precautionary Statements P210-P261-P281-P301 + P310-P305 + P351 + P338-P331
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F,C
Risk Phrases 11-29-34
Safety Phrases S16-S26-S43-S45-S36-S37-S39
RIDADR UN 2925 4.1/PG 2
WGK Germany 3
Packaging Group II

 Synthetic Route

~99%

Chlorotris(trimethylsilyl)silane Structure

Chlorotris(trim...

CAS#:5565-32-2

Literature: Pongkittiphan, Veerachai; Theodorakis, Emmanuel A.; Chavasiri, Warinthorn Tetrahedron Letters, 2009 , vol. 50, # 36 p. 5080 - 5082

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Chlorotris(trimethylsilyl)silane Structure

Chlorotris(trim...

CAS#:5565-32-2

Literature: Rouquet, Guy; Robert, Frederic; Mereau, Raphael; Castet, Frederic; Landais, Yannick Chemistry - A European Journal, 2011 , vol. 17, # 49 p. 13904 - 13911

~92%

Chlorotris(trimethylsilyl)silane Structure

Chlorotris(trim...

CAS#:5565-32-2

Literature: Kornev, A. N.; Chesnokova, T. A.; Semenov, V. V.; Kurskii, Yu. A. Russian Chemical Bulletin, 1995 , vol. 44, # 6 p. 1107 - 1110 Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 6 p. 1146 - 1149

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Chlorotris(trimethylsilyl)silane Structure

Chlorotris(trim...

CAS#:5565-32-2

Literature: Journal of Organometallic Chemistry, , vol. 5, p. 199 - 200

~%

Chlorotris(trimethylsilyl)silane Structure

Chlorotris(trim...

CAS#:5565-32-2

Literature: Chemistry - A European Journal, , vol. 17, # 49 p. 13904 - 13911

~%

Chlorotris(trimethylsilyl)silane Structure

Chlorotris(trim...

CAS#:5565-32-2

Literature: Russian Chemical Bulletin, , vol. 44, # 6 p. 1107 - 1110 Izvestiya Akademi Nauk, Seriya Khimicheskaya, , # 6 p. 1146 - 1149

~%

Chlorotris(trimethylsilyl)silane Structure

Chlorotris(trim...

CAS#:5565-32-2

Literature: Dalton Transactions, , # 42 p. 9304 - 9311

 Synonyms

2-Chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
Trisilane, 2-chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
Chlorotris(trimethylsilyl)silane
chloro-tris(trimethylsilyl)silane
MFCD01321222