Decyl chloroformate

Modify Date: 2024-01-02 15:16:13

Decyl chloroformate Structure
Decyl chloroformate structure
Common Name Decyl chloroformate
CAS Number 55488-51-2 Molecular Weight 220.73600
Density 0.956 g/mL at 25ºC(lit.) Boiling Point 226-227ºC(lit.)
Molecular Formula C11H21ClO2 Melting Point N/A
MSDS Chinese Flash Point >230 °F
Symbol GHS05
GHS05
Signal Word Danger

 Use of Decyl chloroformate


Decyl chloroformate is an n-alkyl chloroformate derivative that can be prepared by reacting decyl alcohol with triphosgene. Decyl chloroformate may be used in the preparation of (S)-(+)-N-decoxycarbonyl-leucine, a chiral surfactant. It may also be used to synthesize decyl chloride via decarboxylation in the presence of dimethylformamide.

 Names

Name decyl carbonochloridate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.956 g/mL at 25ºC(lit.)
Boiling Point 226-227ºC(lit.)
Molecular Formula C11H21ClO2
Molecular Weight 220.73600
Flash Point >230 °F
Exact Mass 220.12300
PSA 26.30000
LogP 4.50250
Index of Refraction n20/D 1.438(lit.)

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C
Risk Phrases 34
Safety Phrases S26-S27-S36-S37-S39
RIDADR UN 1760 8/PG 1
HS Code 2915900090

 Synthetic Route

~80%

Decyl chloroformate Structure

Decyl chloroformate

CAS#:55488-51-2

Literature: Wong; Hungtington; Konishi; Rytting; Higuchi Journal of Pharmaceutical Sciences, 1988 , vol. 77, # 11 p. 967 - 971

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles2

More Articles
Carbamate chiral surfactants for capillary electrophoresis. Ding W and Fritz JS.

J. Chromatogr. A. 831(2) , 311-320, (1999)

Dimethylformamide-catalyzed decarboxylation of alkyl chloroformates. A synthesis of primary alkyl chlorides. Richter R and Tucker B.

J. Org. Chem. 48(15) , 2625-2627, (1983)

 Synonyms

decyloxycarbonyl chloride
MFCD00126853
n-decyl chloroformate
decanyl chloroformate
Chloroformic Acid Decyl Ester
EINECS 259-668-9
Decyl chloroformate
chloroformic acid n-decyl ester
chlorocarbonic acid decyl ester