methyl 3-phenoxybenzoate

Modify Date: 2024-01-08 17:45:10

methyl 3-phenoxybenzoate Structure
methyl 3-phenoxybenzoate structure
Common Name methyl 3-phenoxybenzoate
CAS Number 50789-43-0 Molecular Weight 228.24300
Density 1.153g/cm3 Boiling Point 334.4ºC at 760 mmHg
Molecular Formula C14H12O3 Melting Point N/A
MSDS N/A Flash Point 138.2ºC

 Names

Name methyl 3-phenoxybenzoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.153g/cm3
Boiling Point 334.4ºC at 760 mmHg
Molecular Formula C14H12O3
Molecular Weight 228.24300
Flash Point 138.2ºC
Exact Mass 228.07900
PSA 35.53000
LogP 3.26550
Index of Refraction 1.565

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DH6294500
CHEMICAL NAME :
Benzoic acid, 3-phenoxy-, methyl ester
CAS REGISTRY NUMBER :
50789-43-0
BEILSTEIN REFERENCE NO. :
2111581
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C14-H12-O3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 26,954,1978

 Safety Information

Hazard Codes Xi
HS Code 2918990090

 Synthetic Route

~97%

methyl 3-phenoxybenzoate Structure

methyl 3-phenox...

CAS#:50789-43-0

Literature: Burgos, Carlos H.; Barder, Timothy E.; Huang, Xiaohua; Buchwald, Stephen L. Angewandte Chemie - International Edition, 2006 , vol. 45, # 26 p. 4321 - 4326

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methyl 3-phenoxybenzoate Structure

methyl 3-phenox...

CAS#:50789-43-0

Literature: Rhone-Poulenc Industries Patent: US4288386 A1, 1981 ;

~67%

methyl 3-phenoxybenzoate Structure

methyl 3-phenox...

CAS#:50789-43-0

Literature: Zhu, Yan; Yan, Hong; Lu, Linhua; Liu, Defu; Rong, Guangwei; Mao, Jincheng Journal of Organic Chemistry, 2013 , vol. 78, # 19 p. 9898 - 9905

~59%

methyl 3-phenoxybenzoate Structure

methyl 3-phenox...

CAS#:50789-43-0

Literature: Atta, Ananta Kumar; Kim, Seul-Bi; Cho, Dong-Gyu Bulletin of the Korean Chemical Society, 2011 , vol. 32, # 6 p. 2070 - 2072

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methyl 3-phenoxybenzoate Structure

methyl 3-phenox...

CAS#:50789-43-0

Literature: Marrocco, Matt; Brilmyer, George Journal of Organic Chemistry, 1983 , vol. 48, # 9 p. 1487 - 1491

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methyl 3-phenoxybenzoate Structure

methyl 3-phenox...

CAS#:50789-43-0

Literature: Nagarapu, Lingaiah; Ravirala, Narender; Akkewar, Dattatray M. Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1998 , vol. 37, # 12 p. 1254 - 1257

~%

methyl 3-phenoxybenzoate Structure

methyl 3-phenox...

CAS#:50789-43-0

Literature: Nagarapu, Lingaiah; Ravirala, Narender; Akkewar, Dattatray M. Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1998 , vol. 37, # 12 p. 1254 - 1257

~%

methyl 3-phenoxybenzoate Structure

methyl 3-phenox...

CAS#:50789-43-0

Literature: Nagarapu, Lingaiah; Ravirala, Narender; Akkewar, Dattatray M. Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1998 , vol. 37, # 12 p. 1254 - 1257

~%

methyl 3-phenoxybenzoate Structure

methyl 3-phenox...

CAS#:50789-43-0

Literature: Tomita; Ikawa Yakugaku Zasshi, 1954 , vol. 74, p. 1065,1067 Chem.Abstr., 1955 , p. 11592

 Customs

HS Code 2918990090
Summary 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

3-Phenoxy-benzoesaeure-methylester
methyl meta-phenoxybenzoate
Benzoic acid,3-phenoxy-,methyl ester
3-phenoxy-benzoic acid methyl ester
EINECS 256-764-2
Methyl-3-phenoxybenzoate
3-Methoxycarbonyldiphenyl ether