Furfuryl isothiocyanate structure
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Common Name | Furfuryl isothiocyanate | ||
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CAS Number | 4650-60-6 | Molecular Weight | 139.17500 | |
Density | 1.39 | Boiling Point | 64 °C | |
Molecular Formula | C6H5NOS | Melting Point | N/A | |
MSDS | Chinese USA | Flash Point | 64-68°C/2mm |
Name | 2-furfuryl isothiocyanate |
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Synonym | More Synonyms |
Density | 1.39 |
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Boiling Point | 64 °C |
Molecular Formula | C6H5NOS |
Molecular Weight | 139.17500 |
Flash Point | 64-68°C/2mm |
Exact Mass | 139.00900 |
PSA | 57.59000 |
LogP | 1.88240 |
Index of Refraction | 1.5655 |
Synonym:2-Furfuryl isothiocyanat Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.Moisture sensitive. Potential Health Effects Eye: Causes eye irritation. Lachrymator (substance which increases the flow of tears). Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 4650-60-6: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: orange - dark brown Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 64 - 68 deg C @2mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.39 Molecular Formula: C6H5NOS Molecular Weight: 139 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents, acids, bases. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide, acrid smoke and fumes. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 4650-60-6 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Furylmethyl isothiocyanate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2810 Packing Group: III IMO Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing Group: III RID/ADR Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 4650-60-6: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 4650-60-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 4650-60-6 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xn:Harmful; |
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Risk Phrases | R20/21/22;R36/37/38 |
Safety Phrases | S26-S36/37/39 |
RIDADR | 2810 |
Packaging Group | III |
Hazard Class | 8 |
HS Code | 2932190090 |
~69% Furfuryl isothi... CAS#:4650-60-6 |
Literature: Nath, Jayashree; Ghosh, Harisadhan; Yella, Mamesh; Patel, Bhisma K. European Journal of Organic Chemistry, 2009 , # 12 p. 1849 - 1851 |
~94% Furfuryl isothi... CAS#:4650-60-6 |
Literature: Li, Zheng-Yi; Ma, Hong-Zhao; Han, Chen; Xi, Hai-Tao; Meng, Qi; Chen, Xin; Sun, Xiao-Qiang Synthesis (Germany), 2013 , vol. 45, # 12 art. no. SS-2013-F0228-OP, p. 1667 - 1674 |
~% Furfuryl isothi... CAS#:4650-60-6 |
Literature: American Cyanamid Company Patent: US4267191 A1, 1981 ; Title/Abstract Full Text Show Details American Cyanamid Company Patent: US4313885 A1, 1982 ; |
~82% Furfuryl isothi... CAS#:4650-60-6 |
Literature: Li, Zheng-Yi; Ma, Hong-Zhao; Han, Chen; Xi, Hai-Tao; Meng, Qi; Chen, Xin; Sun, Xiao-Qiang Synthesis (Germany), 2013 , vol. 45, # 12 art. no. SS-2013-F0228-OP, p. 1667 - 1674 |
~% Furfuryl isothi... CAS#:4650-60-6 |
Literature: Muccioli, Giulio G.; Martin, Diana; Scriba, Gerhard K. E.; Poppitz, Wolfgang; Poupaert, Jacques H.; Wouters, Johan; Lambert, Didier M. Journal of Medicinal Chemistry, 2005 , vol. 48, # 7 p. 2509 - 2517 |
~% Furfuryl isothi... CAS#:4650-60-6 |
Literature: Li, Zheng-Yi; Ma, Hong-Zhao; Han, Chen; Xi, Hai-Tao; Meng, Qi; Chen, Xin; Sun, Xiao-Qiang Synthesis (Germany), 2013 , vol. 45, # 12 art. no. SS-2013-F0228-OP, p. 1667 - 1674 |
HS Code | 2932190090 |
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Summary | 2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0% |
2-Furfurylisothiocyanate |
2-furanylmethyl isothiocyanate |
Furfurylisothiocyanate |
2-FURYLMETHYL ISOTHIOCYANATE |
EINECS 225-079-0 |
Furfuryl isothiocyanate |
MFCD00014112 |