o-Toluenesulfonyl fluoride

Modify Date: 2024-01-17 18:05:09

o-Toluenesulfonyl fluoride Structure
o-Toluenesulfonyl fluoride structure
Common Name o-Toluenesulfonyl fluoride
CAS Number 444-31-5 Molecular Weight 174.19300
Density 1.276g/cm3 Boiling Point 227.4ºC at 760mmHg
Molecular Formula C7H7FO2S Melting Point N/A
MSDS Chinese USA Flash Point 91.3ºC

 Names

Name 2-methylbenzenesulfonyl fluoride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.276g/cm3
Boiling Point 227.4ºC at 760mmHg
Molecular Formula C7H7FO2S
Molecular Weight 174.19300
Flash Point 91.3ºC
Exact Mass 174.01500
PSA 42.52000
LogP 2.73400

 Safety Information

Hazard Codes C
Safety Phrases 26-36/37/39-45
HS Code 2904909090

 Synthetic Route

~%

o-Toluenesulfonyl fluoride Structure

o-Toluenesulfon...

CAS#:444-31-5

Literature: Halperin et al. Journal of the American Chemical Society, 1951 , vol. 73, p. 1857

~92%

o-Toluenesulfonyl fluoride Structure

o-Toluenesulfon...

CAS#:444-31-5

Literature: Arapov, O. V.; Rudenko, A. P.; Zarubin, M. Ya. Journal of Organic Chemistry USSR (English Translation), 1985 , vol. 21, # 1 p. 152 - 163 Zhurnal Organicheskoi Khimii, 1985 , vol. 21, # 1 p. 168 - 180

~%

o-Toluenesulfonyl fluoride Structure

o-Toluenesulfon...

CAS#:444-31-5

Literature: Kantlehner, Willi; Leonhardt, Sylvia; Ziegler, Georg; Scherr, Oliver; Kress, Ralf; Goeppert, Alain; Sommer, Jean Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2007 , vol. 62, # 8 p. 995 - 1014

~%

o-Toluenesulfonyl fluoride Structure

o-Toluenesulfon...

CAS#:444-31-5

Literature: Vigalok, I. V.; Petrova, G. G.; Lukashina, S. G.; Vigalok, A. A.; Levin, Ya. A. Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 7 p. 1239 - 1243 Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 7 p. 1442 - 1447

~%

o-Toluenesulfonyl fluoride Structure

o-Toluenesulfon...

CAS#:444-31-5

Literature: Steinkopf Journal fuer Praktische Chemie (Leipzig), 1927 , vol. <2> 117, p. 21

~18%

Detail
Literature: Krylov, E. N.; Khokhlova, S. G. J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 2 p. 390 - 393,341 - 343

 Customs

HS Code 2904909090
Summary HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Synonyms

2-methyl-benzenesulfonyl fluoride
Toluol-2-sulfonylfluorid
toluene-2-sulfonyl fluoride
2-methylphenylsulfonyl fluoride
phenylmethylsulfonyl fluoride
o-toluenesulfonyl fluoride