1-(4'-Bromophenoxy)-1-ethoxyethane

Modify Date: 2024-01-14 22:03:17

1-(4'-Bromophenoxy)-1-ethoxyethane Structure
1-(4'-Bromophenoxy)-1-ethoxyethane structure
Common Name 1-(4'-Bromophenoxy)-1-ethoxyethane
CAS Number 39255-20-4 Molecular Weight 245.11300
Density 1.318g/cm3 Boiling Point 130-132ºC
Molecular Formula C10H13BrO2 Melting Point N/A
MSDS N/A Flash Point 106.1ºC

 Names

Name 1-bromo-4-(2-ethoxyethoxy)benzene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.318g/cm3
Boiling Point 130-132ºC
Molecular Formula C10H13BrO2
Molecular Weight 245.11300
Flash Point 106.1ºC
Exact Mass 244.01000
PSA 18.46000
LogP 3.21040
Index of Refraction 1.521-1.523
Storage condition 2-8°C

 MSDS

Name: 1-(4'-Bromophenoxy)-1-Ethoxyethane Material Safety Data Sheet
Synonym: None known.
CAS: 39255-20-4
Section 1 - Chemical Product MSDS Name: 1-(4'-Bromophenoxy)-1-Ethoxyethane Material Safety Data Sheet
Synonym: None known.
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
39255-20-4 1-(4'-Bromophenoxy)-1-Ethoxyethane ca 100 254-383-6
Hazard Symbols: XI
Risk Phrases: 36/37
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes and respiratory system.The toxicological properties of this material have not been fully investigated. Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
SECTION 4 - FIRST AID MEASURES
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.
SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 39255-20-4: Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: green-yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 130.0 - 132.0 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H13BrO2
Molecular Weight: 245.12
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide, bromine fumes.
Hazardous Polymerization: Has not been reported
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 39255-20-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-(4'-Bromophenoxy)-1-Ethoxyethane - Not listed by ACGIH, IARC, or NTP.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material.
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37 Irritating to eyes and respiratory system.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 39255-20-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 39255-20-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 39255-20-4 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 4/05/1997 Revision #7 Date: 3/04/2004 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R36/37
Safety Phrases 24/25
HS Code 2909309090

 Synthetic Route

~85%

1-(4'-Bromophenoxy)-1-ethoxyethane Structure

1-(4'-Bromophen...

CAS#:39255-20-4

Literature: PHARMACIA CORPORATION Patent: WO2004/811 A1, 2003 ; Location in patent: Page 124-125 ; WO 2004/000811 A1

~%

1-(4'-Bromophenoxy)-1-ethoxyethane Structure

1-(4'-Bromophen...

CAS#:39255-20-4

Literature: Takeda Chemical Industries, Ltd. Patent: US6235771 B1, 2001 ;

~73%

1-(4'-Bromophenoxy)-1-ethoxyethane Structure

1-(4'-Bromophen...

CAS#:39255-20-4

Literature: Seto, Masaki; Aramaki, Yoshio; Okawa, Tomohiro; Miyamoto, Naoki; Aikawa, Katsuji; Kanzaki, Naoyuki; Niwa, Shin-Ichi; Iizawa, Yuji; Baba, Masanori; Shiraishi, Mitsuru Chemical and Pharmaceutical Bulletin, 2004 , vol. 52, # 5 p. 577 - 590

 Customs

HS Code 2909309090
Summary 2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Synonyms

EINECS 254-383-6