Methyl 2-bromobutyrate

Modify Date: 2024-01-02 16:56:49

Methyl 2-bromobutyrate Structure
Methyl 2-bromobutyrate structure
Common Name Methyl 2-bromobutyrate
CAS Number 3196-15-4 Molecular Weight 181.028
Density 1.4±0.1 g/cm3 Boiling Point 171.0±0.0 °C at 760 mmHg
Molecular Formula C5H9BrO2 Melting Point N/A
MSDS Chinese USA Flash Point 68.3±0.0 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger

 Names

Name methyl 2-bromobutanoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 171.0±0.0 °C at 760 mmHg
Molecular Formula C5H9BrO2
Molecular Weight 181.028
Flash Point 68.3±0.0 °C
Exact Mass 179.978592
PSA 26.30000
LogP 1.72
Vapour Pressure 1.4±0.3 mmHg at 25°C
Index of Refraction 1.454
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger
Hazard Statements H225-H315
Precautionary Statements P210
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)
Hazard Codes C:Corrosive
Risk Phrases R34
Safety Phrases S26-S36/37/39-S45-S24-S16-S9
RIDADR UN 3265 8/PG 3
WGK Germany 3
Packaging Group III
Hazard Class 8
HS Code 2915600000

 Synthetic Route

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Methyl 2-bromobutyrate Structure

Methyl 2-bromob...

CAS#:3196-15-4

Literature: Archiv der Pharmazie (Weinheim, Germany), , vol. 292, p. 565,574, 577

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Methyl 2-bromobutyrate Structure

Methyl 2-bromob...

CAS#:3196-15-4

Literature: Annales de Chimie (Cachan, France), , vol. <5>17, p. 532

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Methyl 2-bromobutyrate Structure

Methyl 2-bromob...

CAS#:3196-15-4

Literature: Bulletin de la Societe Chimique de France, , p. 4055 - 4062

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Methyl 2-bromobutyrate Structure

Methyl 2-bromob...

CAS#:3196-15-4

Literature: Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 259, p. 151 - 153

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles2

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Copper(I) mediated cross-coupling of amino acid derived organozinc reagents with acid chlorides.

Org. Biomol. Chem. 4(9) , 1796-805, (2006)

This paper describes the development of a straightforward experimental protocol for copper-mediated cross-coupling of amino acid derived beta-amido-alkylzinc iodides 1 and 3 with a range of acid chlor...

An efficient enantioselective synthesis of an indane acetic acid derivative: methyl (2S)-2-[(1S)-5-hydroxy-2, 3-dihydro-1H-inden-1-yl] butanoate. Zhang M, et al.

Tetrahedron Asymmetry 14(22) , 3447-53, (2003)

 Synonyms

methyl ester of 2-bromobutyric acid
Butanoic acid, 2-bromo-, methyl ester
Methyl 2-bromobutyrate
2-bromobutylic acid methyl ester
2-Bromo methyl butyrate
2-bromobutanoic acid methyl ester
EINECS 221-699-0
2-Bromobutyric Acid Methyl Ester
Methyl 2-bromobutanoate
methyl bromobutyrate
Butanoic acid,2-bromo-,methyl ester
MFCD00009666