alpha-(N,N-Dimethylamino)ethylferrocene

Modify Date: 2024-01-09 19:07:33

alpha-(N,N-Dimethylamino)ethylferrocene Structure
alpha-(N,N-Dimethylamino)ethylferrocene structure
Common Name alpha-(N,N-Dimethylamino)ethylferrocene
CAS Number 31904-34-4 Molecular Weight 257.15200
Density 1.222 Boiling Point 120-121°C 0,7mm
Molecular Formula C14H19FeN Melting Point N/A
MSDS N/A Flash Point >110°C

 Names

Name (+)-N,N-Dimethyl-1-ferrocenylethylamine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.222
Boiling Point 120-121°C 0,7mm
Molecular Formula C14H19FeN
Molecular Weight 257.15200
Flash Point >110°C
Exact Mass 257.08700
PSA 3.24000
LogP 2.36080
Appearance of Characters liquid | orange
Index of Refraction n20/D 1.587
Water Solubility Not miscible or difficult to mix in water.

 MSDS


Section 1: Product Identification
Chemical Name:alpha-(N,N-Dimethylamino)ethylferrocene, 98%
CAS Registry Number:31904-34-4
Formula:(C5H5)Fe(C5H4CH(CH3)N(CH3)2)
EINECS Number:None
Chemical Family:metallocene
Synonym:bis-alpha-(N,N-Dimethylamino)ethylcyclopentadienyl iron

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound31904-34-4100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation of dust. Eyes and skin.
Eye Contact:Causes moderate irritation of the eyes.
Skin Contact:Causes slight to moderate irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No specific information on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards
Chronic Health Affects:
may be present.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry area away from heat and direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:orange liq.
Molecular Weight:257.16
Melting Point:no data
Boiling Point:110°C/0.45mm
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:Oxidizing agents and halogens
Decomposition Products:carbon dioxide, carbon monoxide, nitrogen oxides, organic fumes, and iron oxide

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn: Harmful;
Risk Phrases R36/38
Safety Phrases S26-S36

 Synthetic Route

~88%

alpha-(N,N-Dimethylamino)ethylferrocene Structure

alpha-(N,N-Dime...

CAS#:31904-34-4

Literature: Gokel, G.; Hoffmann, P.; Klusacek, H.; Marquarding, D.; Ruch, E.; Ugi, I. Angewandte Chemie, International Edition in English, 1970 , vol. 9, p. 64 - 65 Full Text Show Details Gokel, G.; Hoffmann, P.; Klusacek, H.; Marquarding, D.; Ruch, E.; Ugi, I. Angewandte Chemie, 1970 , vol. 82, p. 77 - 78 Full Text Show Details Gmelin Handbook: Fe: Org.Verb.A4, 5.1.4.1.3.3, page 52 - 55

~53%

alpha-(N,N-Dimethylamino)ethylferrocene Structure

alpha-(N,N-Dime...

CAS#:31904-34-4

Literature: Gmelin Handbook: Fe: Org.Verb.A4, 5.1.4.1.3.3, page 52 - 55

~%

alpha-(N,N-Dimethylamino)ethylferrocene Structure

alpha-(N,N-Dime...

CAS#:31904-34-4

Literature: Butler, Ian R.; Cullen, William R. Canadian Journal of Chemistry, 1983 , vol. 61, p. 2354 - 2358

~60%

alpha-(N,N-Dimethylamino)ethylferrocene Structure

alpha-(N,N-Dime...

CAS#:31904-34-4

Literature: Gmelin Handbook: Fe: Org.Verb.A4, 5.1.4.1.3.3, page 52 - 55

~%

alpha-(N,N-Dimethylamino)ethylferrocene Structure

alpha-(N,N-Dime...

CAS#:31904-34-4

Literature: Angewandte Chemie, International Edition in English, , vol. 9, p. 64 - 65 Angewandte Chemie, , vol. 82, p. 77 - 78 Fe: Org.Verb.A4, 5.1.4.1.1.2, page 10 - 22

~%

alpha-(N,N-Dimethylamino)ethylferrocene Structure

alpha-(N,N-Dime...

CAS#:31904-34-4

Literature: Dixneuf, P.; Dabard, R. Bulletin de la Societe Chimique de France, 1972 , p. 2838 - 2847 Full Text Show Details Gmelin Handbook: Fe: Org.Verb.A4, 5.1.4.1.3.3, page 52 - 55

~%

alpha-(N,N-Dimethylamino)ethylferrocene Structure

alpha-(N,N-Dime...

CAS#:31904-34-4

Literature: Bulletin de la Societe Chimique de France, , p. 2838 - 2847 Fe: Org.Verb.A4, 5.1.4.1.3.3, page 52 - 55

 Synonyms

EINECS 250-862-9
α-(N,N-Dimethylamino)ethylferrocene
N,N-Dimethyl-1-ferrocenylethylamine
(+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE
MFCD01074444