bis(benzylsulfanyl)methanethione

Modify Date: 2024-01-06 17:33:07

bis(benzylsulfanyl)methanethione Structure
bis(benzylsulfanyl)methanethione structure
Common Name bis(benzylsulfanyl)methanethione
CAS Number 26504-29-0 Molecular Weight 290.46700
Density 1.249g/cm3 Boiling Point 469ºC at 760 mmHg
Molecular Formula C15H14S3 Melting Point 29-33 °C
MSDS Chinese USA Flash Point 237.5ºC
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name bis(benzylsulfanyl)methanethione
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.249g/cm3
Boiling Point 469ºC at 760 mmHg
Melting Point 29-33 °C
Molecular Formula C15H14S3
Molecular Weight 290.46700
Flash Point 237.5ºC
Exact Mass 290.02600
PSA 82.69000
LogP 5.13810
Vapour Pressure 1.6E-08mmHg at 25°C
Index of Refraction 1.683
Storage condition 2-8°C

 MSDS


Section 1: Product Identification
Chemical Name:S,S-Dibenzyltrithiocarbonate, min. 97%
CAS Registry Number:26504-29-0
Formula:C15H14S3
EINECS Number:none
Chemical Family:organosulfur compound
Synonym:Bis(benzylsulfanyl)methanethione; Trithiocarbonic acid dibenzyl ester

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound26504-29-0100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unususal fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Store cold. Prolonged
Handling and Storage:
exposure to air and moisture will degrade the material.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:dark yellow liquid
Molecular Weight:290.47
Melting Point:no data
Boiling Point:172°C /0.06 mm
Vapor Pressure:no data
Specific Gravity:no data
Odor:slight rotten egg smell
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:moisture sensitive (store cold)
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents and halogens
Decomposition Products:carbon monoxide, carbon dioxide, sulfur oxides and organic fumes

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H317-H319
Precautionary Statements P280-P305 + P351 + P338
Hazard Codes Xi
Risk Phrases 36/38-43
Safety Phrases 26-36/37
RIDADR NONH for all modes of transport
HS Code 2930909090

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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 Synonyms

trithiocarbonic acid dibenzyl ester
dibenzyl trithiocarbonate
S,S-Dibenzyl trithiocarbonate
dibenzyl carbonotrithioate
S,S-DIBENZYLTRITHIOCARBONATE