Methyl nitroacetate structure
|
Common Name | Methyl nitroacetate | ||
|---|---|---|---|---|
| CAS Number | 2483-57-0 | Molecular Weight | 119.076 | |
| Density | 1.3±0.1 g/cm3 | Boiling Point | 196.5±0.0 °C at 760 mmHg | |
| Molecular Formula | C3H5NO4 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 105.0±0.0 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | methyl 2-nitroacetate |
|---|---|
| Synonym | More Synonyms |
| Density | 1.3±0.1 g/cm3 |
|---|---|
| Boiling Point | 196.5±0.0 °C at 760 mmHg |
| Molecular Formula | C3H5NO4 |
| Molecular Weight | 119.076 |
| Flash Point | 105.0±0.0 °C |
| Exact Mass | 119.021858 |
| PSA | 72.12000 |
| LogP | 0.34 |
| Vapour Pressure | 0.4±0.3 mmHg at 25°C |
| Index of Refraction | 1.418 |
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi:Irritant; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | S26-S36-S37/39 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 2 |
| RTECS | AJ1093000 |
| HS Code | 2915900090 |
| HS Code | 2915900090 |
|---|---|
| Summary | 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0% |
|
Experimental and theoretical studies of Diels-Alder reaction between methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate and cyclopentadiene. Jasinski R, et al.
Monatsh. Chem 144(3) , 327-35, (2013)
|
|
|
Catalytic intermolecular allylic C-H alkylation.
J. Am. Chem. Soc. 130 , 14090-14091, (2008) The first electrophilic Pd(II)-catalyzed allylic C H alkylation is reported, providing a novel method for formation of sp3-sp3 C C bonds directly from C H bonds. A wide range of aromatic and heteroaro... |
|
|
Expedient synthesis of cyclopropane alpha-amino acids by the catalytic asymmetric cyclopropanation of alkenes using iodonium ylides derived from methyl nitroacetate.
J. Am. Chem. Soc. 127(51) , 18014-5, (2005) A highly enantioselective (up to 97.5% ee) and diastereoselective (95:5 dr trans/cis) Cu(I)-catalyzed cyclopropanation of alkenes using phenyliodonium ylide generated in situ from iodosobenzene and me... |
| Acetic acid, 2-nitro-, methyl ester |
| methyl 2-nitroethanoate |
| MFCD00075480 |
| Methyl 2-nitroacetate |
| Methyl nitroacetate |
| Methyl α nitroacetate |
| EINECS 219-622-0 |
| NO2CH2CO2Me |
| ACETIC ACID,NITRO-,METHYL ESTER |
| Nitroacetic acid methyl ester |