Butyl glycidyl ether

Modify Date: 2024-01-01 18:43:34

Butyl glycidyl ether Structure
Butyl glycidyl ether structure
 Common Name Butyl glycidyl ether
CAS Number 2426-08-6 Molecular Weight 130.185
Density 0.9±0.1 g/cm3 Boiling Point 177.0±0.0 °C at 760 mmHg
Molecular Formula C7H14O2 Melting Point N/A
MSDS Chinese USA Flash Point 54.4±0.0 °C
Symbol GHS02 GHS05 GHS06 GHS08
GHS02, GHS05, GHS06, GHS08		 Signal Word Danger

 Names

Name Butyl glycidyl ether
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 177.0±0.0 °C at 760 mmHg
Molecular Formula C7H14O2
Molecular Weight 130.185
Flash Point 54.4±0.0 °C
Exact Mass 130.099380
PSA 21.76000
LogP 1.42
Vapour Pressure 1.4±0.3 mmHg at 25°C
Index of Refraction 1.433
Stability Stable. May form explosive peroxides on contact with air. Store under inert gas.
Water Solubility 2 g/100 mL

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TX4200000
CHEMICAL NAME :
Propane, 1-butoxy-2,3-epoxy-
CAS REGISTRY NUMBER :
2426-08-6
BEILSTEIN REFERENCE NO. :
0103668
LAST UPDATED :
199712
DATA ITEMS CITED :
50
MOLECULAR FORMULA :
C7-H14-O2
MOLECULAR WEIGHT :
130.21
WISWESSER LINE NOTATION :
T3OTJ B1O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1660 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - respiratory depression
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1030 ppm/8H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Gastrointestinal - changes in structure or function of salivary glands Lungs, Thorax, or Respiration - dyspnea
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2150 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1140 mg/kg
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Behavioral - ataxia
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1530 mg/kg
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Behavioral - ataxia
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
260 mg/m3
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - respiratory depression
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
700 mg/kg
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Behavioral - ataxia
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2520 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
DOSE :
36 gm/kg
SEX/DURATION :
male 24 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetal death
TYPE OF TEST :
Micronucleus test

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Lung
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 249,55,1991 *** REVIEWS *** ACGIH TLV-TWA 133 mg/m3 (25 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 50 ppm (270 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,33,1971 OSHA PEL (Gen Indu):8H TWA 50 ppm (270 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 50 ppm (270 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 50 ppm (270 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 50 ppm (270 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 25 ppm (135 mg/m3) JAN 1993 OEL-BELGIUM:TWA 25 ppm (133 mg/m3) JAN 1993 OEL-DENMARK:TWA 6 ppm (30 mg/m3) JAN 1993 OEL-FINLAND:STEL 25 ppm (135 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 25 ppm (135 mg/m3) JAN 1993 OEL-GERMANY;Skin;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 25 ppm (135 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 50 ppm (270 mg/m3) JAN 1993 OEL-SWEDEN:TWA 10 ppm (50 mg/m3);STEL 15 ppm (80 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 25 ppm (135 mg/m3);STEL 50 ppm;Skin JAN 1993 OEL-TURKEY:TWA 50 ppm (270 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 25 ppm (135 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO BUTYL GLYCIDYL ETHER-air:CL 5.6 ppm/15M REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 14720 No. of Facilities: 1596 (estimated) No. of Industries: 37 No. of Occupations: 45 No. of Employees: 19839 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 14720 No. of Facilities: 2593 (estimated) No. of Industries: 56 No. of Occupations: 57 No. of Employees: 60217 (estimated) No. of Female Employees: 14929 (estimated)

 Safety Information

Symbol GHS02 GHS05 GHS06 GHS08
GHS02, GHS05, GHS06, GHS08
Signal Word Danger
Hazard Statements H226-H302-H314-H317-H331-H335-H341-H350-H412
Precautionary Statements P201-P261-P273-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn:Harmful;
Risk Phrases R10;R20/22;R37;R40;R43;R52/53;R68
Safety Phrases S24/25-S36/37-S61
RIDADR UN 3271 3/PG 3
WGK Germany 2
RTECS TX4200000
Packaging Group III
Hazard Class 3
HS Code 29109000

 Synthetic Route

Allyl Butyl Ether structure

Allyl Butyl Ether

CAS#:3739-64-8

~70%

Butyl glycidyl ether Structure

Butyl glycidyl ether

CAS#:2426-08-6
Literature: Mizuno, Noritaka; Kamata, Keigo; Yamaguchi, Kazuya Catalysis Today, 2012 , vol. 185, # 1 p. 157 - 161
N/A structure

N/A

CAS#:98451-40-2

~76%

Butyl glycidyl ether Structure

Butyl glycidyl ether

CAS#:2426-08-6
Literature: Szeja, W. Synthesis, 1985 , # 10 p. 983 - 985
Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8
Butanol structure

Butanol

CAS#:71-36-3

~75%

Butyl glycidyl ether Structure

Butyl glycidyl ether

CAS#:2426-08-6
Literature: Mouzin, Gilbert; Cousse, Henri; Rieu, Jean-Pierre; Duflos, Alain Synthesis, 1983 , # 2 p. 117 - 119
Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8

~%

Butyl glycidyl ether Structure

Butyl glycidyl ether

CAS#:2426-08-6
Literature: Nippon Kagaku Zasshi, , vol. 77, p. 198 Chem.Abstr., , p. 253
1-Bromobutane structure

1-Bromobutane

CAS#:109-65-9
(2R)-2-[(Trityloxy)methyl]oxirane structure

(2R)-2-[(Trityl...

CAS#:65291-30-7

~%

Butyl glycidyl ether Structure

Butyl glycidyl ether

CAS#:2426-08-6

Triphenylmethane structure

Triphenylmethane

CAS#:519-73-3
Literature: Journal of Organometallic Chemistry, , vol. 660, # 1 p. 6 - 13
1-Bromobutane structure

1-Bromobutane

CAS#:109-65-9
2-((Benzyloxy)methyl)oxirane structure

2-((Benzyloxy)m...

CAS#:2930-05-4

~%

Butyl glycidyl ether Structure

Butyl glycidyl ether

CAS#:2426-08-6

Bibenzyl structure

Bibenzyl

CAS#:103-29-7
Literature: Journal of Organometallic Chemistry, , vol. 660, # 1 p. 6 - 13
2-Propanol,1-butoxy-3-chloro- structure

2-Propanol,1-bu...

CAS#:16224-33-2

~%

Butyl glycidyl ether Structure

Butyl glycidyl ether

CAS#:2426-08-6
Literature: Journal fuer Praktische Chemie (Leipzig), , vol. 333, # 3 p. 413 - 421

 Customs

HS Code 2910900090
Summary 2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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 Synonyms

erl0810
BGE
Epirez 501
1-butoxy-2,3-epoxypropane
Heloxy 61
1,2-Epoxy-3-butoxypropane
ageflexbge
butyl 2,3-epoxypropyl ether
(Butoxymethyl)oxirane
2,3-epoxypropyl n-butyl ether
sipomerbge
MFCD00005145
2-(Butoxymethyl)oxirane
n-butyl glycidyl ether
EINECS 219-376-4
NBGE
Oxirane, 2-(butoxymethyl)-
3-n-butoxy-1,2-epoxypropane
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Related Compounds: More...
n-butyl glycidyl ether
121906-41-0
iso-butyl glycidyl ether
3814-55-9
tert-butyl glycidyl ether
7665-72-7
(R)-t-Butyl glycidyl ether
130232-98-3
Guaiacol glycidyl ether
2210-74-4
TETRAPHENYLOLETHANE GLYCIDYL ETHER
7328-97-4
Allyl glycidyl ether polymer
25639-25-2
phenyl glycidyl ether
71031-03-3
phenyl glycidyl ether
71031-02-2
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