Cerium(IV) tetramethylheptanedionate

Modify Date: 2024-01-11 13:56:43

Cerium(IV) tetramethylheptanedionate Structure
Cerium(IV) tetramethylheptanedionate structure
Common Name Cerium(IV) tetramethylheptanedionate
CAS Number 18960-54-8 Molecular Weight 506.65100
Density N/A Boiling Point 140ºC 0,05mm
Molecular Formula C22H38CeO4 Melting Point 275-280ºC
MSDS N/A Flash Point 67.2ºC

 Names

Name cerium,2,2,6,6-tetramethylheptane-3,5-dione

 Chemical & Physical Properties

Boiling Point 140ºC 0,05mm
Melting Point 275-280ºC
Molecular Formula C22H38CeO4
Molecular Weight 506.65100
Flash Point 67.2ºC
Exact Mass 506.18200
PSA 52.60000
LogP 6.02500
Appearance of Characters Powder | red
Vapour Pressure 0.287mmHg at 25°C
Storage condition 2-8℃

 MSDS


Section 1: Product Identification
Chemical Name:Tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionato)cerium (IV),min. 97% (99.9%-Ce) (REO) Ce(TMHD)4
CAS Registry Number:18960-54-8
Formula:Ce(C11H19O2)4
EINECS Number:none
Chemical Family:metal beta-diketonate complexes
Synonym:Dipivaloylmethane, cerium complex

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound18960-54-8100%no datano data

Section 3: Hazards Identification
Emergency Overview:May be irritating to eyes, skin and respiratory tract. Harmful if swallowed.
Primary Routes of Exposure:Ingestion
Eye Contact:May cause slight to mild irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:May be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:May be irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
Inhalation:
breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide or dry powder
If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a sealed container. Keep away from heat and moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:red powder
Molecular Weight:873.2
Melting Point:275-280°
Boiling Point:dec.295°subl. 140°/.05mm
Vapor Pressure:subl. 140°/0.05mm
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents
Decomposition Products:carbon monoxide, carbon dioxide, cerium oxide and organic fumes

SECTION 11: Toxicological Information
RTECS Data:No specific information available on this product.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Risk Phrases 36/37/38
Safety Phrases 26-36/37/39