2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL

Modify Date: 2024-01-08 19:42:56

2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Structure
2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL structure
Common Name 2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
CAS Number 173831-50-0 Molecular Weight 374.429
Density 1.2±0.1 g/cm3 Boiling Point 477.8±45.0 °C at 760 mmHg
Molecular Formula C24H22O4 Melting Point 92-96ºC(lit.)
MSDS Chinese USA Flash Point 126.2±35.6 °C
Symbol GHS05 GHS09
GHS05, GHS09
Signal Word Danger

 Names

Name (R)-2,2’-Bis(methoxymethoxy)-1,1'-binaphthyl
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 477.8±45.0 °C at 760 mmHg
Melting Point 92-96ºC(lit.)
Molecular Formula C24H22O4
Molecular Weight 374.429
Flash Point 126.2±35.6 °C
Exact Mass 374.151794
PSA 36.92000
LogP 4.57
Vapour Pressure 0.0±1.1 mmHg at 25°C
Index of Refraction 1.630

 MSDS


Section 1: Product Identification
Chemical Name:(R)-(+)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl, 98%
CAS Registry Number:173831-50-0
Formula:C24H22O4
EINECS Number:none
Chemical Family:organic alcohol
Synonym:(R)-(+)-2,2'-Bis-methoxymethoxy-[1,1']binaphthalenyl

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound173831-50-0100%no datano data

Section 3: Hazards Identification
Emergency Overview:Dust is irritating to the respiratory tract, skin, eyes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, eyes, inhalation
Eye Contact:Causes mild to moderate irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Dust is irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No specific information is available on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
Inhalation:
breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:dry chemical, carbon dioxide, water or foam.
If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes, carbon monoxide and carbon dioxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a tightly sealed container in a cool, dry place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white powder
Molecular Weight:374.43
Melting Point:100-103°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:slightly soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents
Decomposition Products:carbon monoxide, carbon dioxide and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS05 GHS09
GHS05, GHS09
Signal Word Danger
Hazard Statements H318-H410
Precautionary Statements P273-P280-P305 + P351 + P338-P501
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi,N
Risk Phrases R41
Safety Phrases 26-39-60-61-36/39-25
RIDADR UN 3077 9/PG 3

 Synthetic Route

~99%

2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Structure

2,2'-BIS(METHOX...

CAS#:173831-50-0

Literature: Wu, T. Robert; Shen, Lixin; Chong, J. Michael Organic Letters, 2004 , vol. 6, # 16 p. 2701 - 2704

~83%

2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Structure

2,2'-BIS(METHOX...

CAS#:173831-50-0

Literature: Lv, Na; Xie, Meilan; Gu, Weibing; Ruan, Huanyang; Qiu, Song; Zhou, Chunshan; Cui, Zheng Organic Letters, 2013 , vol. 15, # 10 p. 2382 - 2385

~95%

2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Structure

2,2'-BIS(METHOX...

CAS#:173831-50-0

Literature: Yu, Shanshan; Plunkett, Winston; Kim, Michael; Wu, Elaine; Sabat, Michal; Pu, Lin Journal of Organic Chemistry, 2013 , vol. 78, # 24 p. 12671 - 12680

~%

2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Structure

2,2'-BIS(METHOX...

CAS#:173831-50-0

Literature: Organic Letters, , vol. 15, # 10 p. 2382 - 2385

 Articles1

More Articles
Cox, P. J. et al

Tetrahedron Lett. 33 , 2253, (1992)

 Synonyms

(R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl
(S)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene
(R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene
2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
(R)-(+)-2,2′-Bis(methoxymethoxy)-1,1′-binaphthyl
MFCD03788935
1,1'-Binaphthalene, 2,2'-bis(methoxymethoxy)-
Top Suppliers:I want be here


Get all suppliers and price by the below link:

2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL suppliers

2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL price

Related Compounds: More...
2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
142128-92-5
(r)-(+)-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
74292-20-9
(R)-3-formyl-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
349149-07-1
6,6'-dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
389867-61-2
(s)-3,3'-dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
142010-87-5
(R)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
211560-97-3
(R)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
179866-74-1
(+/-)-3,3'-diphenyl-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
428874-67-3
2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene-3,3'-dicarbaldehyde
176437-91-5
5-((4-Benzylpiperidin-1-yl)(3-methoxyphenyl)methyl)-2-(furan-2-yl)thiazolo[3,2-b][1,2,4]triazol-6-ol
887222-52-8
5-((4-Benzylpiperazin-1-yl)(3-methoxyphenyl)methyl)-2-(furan-2-yl)thiazolo[3,2-b][1,2,4]triazol-6-ol
887222-60-8
2-((3-(3,4-dimethoxybenzyl)-4-oxo-4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)thio)-N-phenylacetamide
877817-23-7
2-((3-(3,4-dimethoxybenzyl)-4-oxo-4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)thio)-N-(p-tolyl)acetamide
877817-24-8
8-[(4-Methoxyphenyl)methyl]-1,6,7-trimethyl-3-(2-piperidylethyl)-1,3,5-trihydr o-4-imidazolino[1,2-h]purine-2,4-dione
886886-95-9
8-(3-chloro-4-methoxyphenyl)-1,7-dimethyl-3-(2-morpholinoethyl)-1H-imidazo[2,1-f]purine-2,4(3H,8H)-dione
896306-76-6
methyl 2-(8-(2,5-dimethoxyphenyl)-1,6,7-trimethyl-2,4-dioxo-1H-imidazo[2,1-f]purin-3(2H,4H,8H)-yl)propanoate
896308-85-3
3-(3-hydroxypropyl)-1-methyl-7-phenyl-8-(p-tolyl)-1H-imidazo[2,1-f]purine-2,4(3H,8H)-dione
896292-49-2
3-(3-hydroxypropyl)-8-(4-methoxyphenyl)-1-methyl-7-phenyl-1H,2H,3H,4H,8H-imidazo[1,2-g]purine-2,4-dione
896296-11-0
8-(4-bromophenyl)-3-(3-hydroxypropyl)-1-methyl-7-phenyl-1H,2H,3H,4H,8H-imidazo[1,2-g]purine-2,4-dione
886898-62-0