Methyl 2,3-dibromopropionate

Modify Date: 2024-01-10 17:49:29

Methyl 2,3-dibromopropionate Structure
Methyl 2,3-dibromopropionate structure
Common Name Methyl 2,3-dibromopropionate
CAS Number 1729-67-5 Molecular Weight 245.89700
Density 1.944 g/mL at 20 °C(lit.) Boiling Point 83-86 °C10 mm Hg(lit.)
Molecular Formula C4H6Br2O2 Melting Point 8ºC
MSDS Chinese USA Flash Point -33 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger

 Names

Name Methyl 2,3-dibromopropionate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.944 g/mL at 20 °C(lit.)
Boiling Point 83-86 °C10 mm Hg(lit.)
Melting Point 8ºC
Molecular Formula C4H6Br2O2
Molecular Weight 245.89700
Flash Point -33 °C
Exact Mass 243.87300
PSA 26.30000
LogP 1.31780
Vapour Pressure 0.243mmHg at 25°C
Index of Refraction n20/D 1.514
Storage condition 2-8°C

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Methyl 2,3-dibromopropionate
Product Name:
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
H319:Causes serious eye irritation
H335:May cause respiratory irritation
P261:Avoid breathing dust/fume/gas/mist/vapours/spray
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
and easy to do – continue rinsing

Section3. Composition/information on ingredients.
Ingredient name:Methyl 2,3-dibromopropionate
CAS number:1729-67-5

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
This product should be handled only by, or under the close supervision of, those properly qualified
Handling:
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Storage:Store in closed vessels, refrigerated.

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
Melting point:No data
Flash point:No data
Density:No data
Molecular formula: C4H6Br2O2
Molecular weight: 245.9

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, hydrogen bromide.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
Non-harzardous for air and ground transportation.

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger
Hazard Statements H225-H315
Precautionary Statements P210
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)
Hazard Codes Xi:Irritant;
Risk Phrases R36/37
Safety Phrases S26-S36-S16
RIDADR UN 2398 3/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 6.1
HS Code 2915900090

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles3

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Tetrahedron Lett. 44(33) , 6313-15, (2003)

Regiospecific and Enantiospecific Ring Opening of Methyl (+)-(1'R, 2R)-and (-)-(1'R, 2S)-1-(2-phenylethanol) Aziridine-2-carboxylates. Gnecco D, et al.

Molecules 5(8) , 998-1003, (2000)

Synthesis of substituted 3, 4-dihydro-2< i> H</i>-pyrido [3, 2-< i> b</i>][1, 4] oxazine as new scaffolds for potential bioactive compounds. Henry N, et al.

Tetrahedron 62(10) , 2405-12, (2006)

 Synonyms

MFCD00017882
EINECS 217-044-3
methyl 2,3-dibromopropanoate
Methyl 2,3-Dibromopropionate