2-Acetoxy-2-phenylacetyl chloride

Modify Date: 2024-01-01 17:43:55

2-Acetoxy-2-phenylacetyl chloride Structure
2-Acetoxy-2-phenylacetyl chloride structure
Common Name 2-Acetoxy-2-phenylacetyl chloride
CAS Number 1638-63-7 Molecular Weight 212.63000
Density 0.943 g/mL at 25 °C(lit.) Boiling Point 125-130 °C10 mm Hg(lit.)
Molecular Formula C10H9ClO3 Melting Point 36ºC
MSDS N/A Flash Point >230 °F

 Names

Name (2-chloro-2-oxo-1-phenylethyl) acetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.943 g/mL at 25 °C(lit.)
Boiling Point 125-130 °C10 mm Hg(lit.)
Melting Point 36ºC
Molecular Formula C10H9ClO3
Molecular Weight 212.63000
Flash Point >230 °F
Exact Mass 212.02400
PSA 43.37000
LogP 2.05620
Vapour Pressure 0.0122mmHg at 25°C
Index of Refraction n20/D 1.514(lit.)
Storage condition 0-6°C

 MSDS

Name: O-Acetylmandelic acid chloride 95% Material Safety Data Sheet
Synonym: 1-(Chloroformyl)benzyl acetate; 2-Acetoxy-2-phenylacetyl chloride
CAS: 1638-63-7
Section 1 - Chemical Product MSDS Name:O-Acetylmandelic acid chloride 95% Material Safety Data Sheet
Synonym:1-(Chloroformyl)benzyl acetate; 2-Acetoxy-2-phenylacetyl chloride

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1638-63-7 O-Acetylmandelic acid chloride 95 216-674-6
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
If water is the only media available, use in flooding amounts. Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out. In case of fire, use carbon dioxide or dry chemical.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Do not allow contact with water. Discard contaminated shoes. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Corrosives area. Keep refrigerated. (Store below 4C/39F.) Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1638-63-7: Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: clear, colorless to pale yellow
Odor: chlorine-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 125-130 deg C @ 10 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 112 deg C ( 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9430 g/ml
Molecular Formula: CH3CO2CH(C6H5)COCl
Molecular Weight: 212.63

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Moisture, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases, alcohols, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1638-63-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
O-Acetylmandelic acid chloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1638-63-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1638-63-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1638-63-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes C: Corrosive;
Risk Phrases R34
Safety Phrases S26-S27-S28-S36/37/39-S45
RIDADR UN 3265 8/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 8
HS Code 2915390090

 Customs

HS Code 2915390090
Summary 2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

 Synonyms

MFCD00000714
2-chloro-2-oxo-1-phenylethyl acetate
Acetylmandelic chloride
O-Acetylmandelic acid chloride
O-ACETYLMANDELIC CHLORIDE
EINECS 216-674-6