(r)-(+)-n-(tert-butoxycarbonyl)-o-

Modify Date: 2025-08-31 23:45:06

(r)-(+)-n-(tert-butoxycarbonyl)-o- Structure
(r)-(+)-n-(tert-butoxycarbonyl)-o- structure
 Common Name (r)-(+)-n-(tert-butoxycarbonyl)-o-
CAS Number 152491-85-5 Molecular Weight 305.48600
Density 0.979g/cm3 Boiling Point 377.301ºC at 760 mmHg
Molecular Formula C14H31NO4Si Melting Point 32-37ºC(lit.)
MSDS Chinese USA Flash Point >230 °F
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name tert-butyl N-[(2R)-1-[tert-butyl(dimethyl)silyl]oxy-3-hydroxypropan-2-yl]carbamate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.979g/cm3
Boiling Point 377.301ºC at 760 mmHg
Melting Point 32-37ºC(lit.)
Molecular Formula C14H31NO4Si
Molecular Weight 305.48600
Flash Point >230 °F
Exact Mass 305.20200
PSA 71.28000
LogP 3.09820
Vapour Pressure 0mmHg at 25°C
Index of Refraction 1.452

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26
RIDADR NONH for all modes of transport
WGK Germany 3

 Synthetic Route

Methyl N-Boc-O-(tert-butyldimethylsilyl)-L-serinate structure

Methyl N-Boc-O-...

CAS#:126645-26-9

~89%

(r)-(+)-n-(tert-butoxycarbonyl)-o- Structure

(r)-(+)-n-(tert...

CAS#:152491-85-5

Literature: Bhowmik, Subhendu; Batra, Sanjay European Journal of Organic Chemistry, 2013 , # 31 p. 7145 - 7151
O-t-butyldimethylsilyl-N-[(1,1-dimethylethoxy)carbonyl]-N-hydroxymethyl-L-serinol structure

O-t-butyldimeth...

CAS#:518986-06-6

~70%

(r)-(+)-n-(tert-butoxycarbonyl)-o- Structure

(r)-(+)-n-(tert...

CAS#:152491-85-5

Literature: Yoo, Dongwon; Seok Oh, Joon; Lee, Dong-Whal; Kim, Young Gyu Journal of Organic Chemistry, 2003 , vol. 68, # 7 p. 2979 - 2982
Di-tert-butyl dicarbonate structure

Di-tert-butyl d...

CAS#:24424-99-5

(R)-2-amino-3-(tert-butyldimethylsiloxy)propan-1-ol structure

(R)-2-amino-3-(...

CAS#:176504-16-8

~91%

(r)-(+)-n-(tert-butoxycarbonyl)-o- Structure

(r)-(+)-n-(tert...

CAS#:152491-85-5

Literature: Bartoli, Giuseppe; Di Antonio, Giustino; Fiocchi, Roberto; Giuli, Sandra; Marcantoni, Enrico; Marcolini, Mauro Synthesis, 2009 , # 6 art. no. Z24108SS, p. 951 - 956
Boc-Ser-OMe structure

Boc-Ser-OMe

CAS#:2766-43-0

~%

(r)-(+)-n-(tert-butoxycarbonyl)-o- Structure

(r)-(+)-n-(tert...

CAS#:152491-85-5

Literature: Colarusso, Stefania; Conte, Immacolata; Di Filippo, Marcello; Ercolani, Caterina; MacKay, Angela C.; Palumbi, Maria Cecilia; Rico Ferreira, Maria Del Rosario; Stansfield, Ian; Zaramella, Simone; Narjes, Frank; Habermann, Joerg Synlett, 2011 , # 11 p. 1527 - 1532
tert-Butyldimethylsilyl chloride structure

tert-Butyldimet...

CAS#:18162-48-6

~%

(r)-(+)-n-(tert-butoxycarbonyl)-o- Structure

(r)-(+)-n-(tert...

CAS#:152491-85-5

Literature: Colarusso, Stefania; Conte, Immacolata; Di Filippo, Marcello; Ercolani, Caterina; MacKay, Angela C.; Palumbi, Maria Cecilia; Rico Ferreira, Maria Del Rosario; Stansfield, Ian; Zaramella, Simone; Narjes, Frank; Habermann, Joerg Synlett, 2011 , # 11 p. 1527 - 1532
N-Boc-(O)-TBS-D-serine structure

N-Boc-(O)-TBS-D...

CAS#:123254-10-4

~%

(r)-(+)-n-(tert-butoxycarbonyl)-o- Structure

(r)-(+)-n-(tert...

CAS#:152491-85-5

Literature: Yoo, Dongwon; Seok Oh, Joon; Lee, Dong-Whal; Kim, Young Gyu Journal of Organic Chemistry, 2003 , vol. 68, # 7 p. 2979 - 2982
(4S)-4-[(t-butyldimethylsilyloxy)methyl]-3-[(1,1-dimethylethoxy)carbonyl]-5-oxazolidinone structure

(4S)-4-[(t-buty...

CAS#:367490-60-6

~%

(r)-(+)-n-(tert-butoxycarbonyl)-o- Structure

(r)-(+)-n-(tert...

CAS#:152491-85-5

Literature: Yoo, Dongwon; Seok Oh, Joon; Lee, Dong-Whal; Kim, Young Gyu Journal of Organic Chemistry, 2003 , vol. 68, # 7 p. 2979 - 2982
O-t-butyldimethylsilyl-N-[(1,1-dimethylethoxy)carbonyl]-N-hydroxymethyl-L-serinal hemiacetal structure

O-t-butyldimeth...

CAS#:518986-05-5

~%

(r)-(+)-n-(tert-butoxycarbonyl)-o- Structure

(r)-(+)-n-(tert...

CAS#:152491-85-5

Literature: Yoo, Dongwon; Seok Oh, Joon; Lee, Dong-Whal; Kim, Young Gyu Journal of Organic Chemistry, 2003 , vol. 68, # 7 p. 2979 - 2982
Di-tert-butyl dicarbonate structure

Di-tert-butyl d...

CAS#:24424-99-5

~%

(r)-(+)-n-(tert-butoxycarbonyl)-o- Structure

(r)-(+)-n-(tert...

CAS#:152491-85-5

Literature: Travins, Jeremy M.; Etzkorn, Felicia A. Tetrahedron Letters, 1998 , vol. 39, # 51 p. 9389 - 9392

 Synonyms

tert-butyl N-[(1R)-2-(tert-butyldimethylsiloxy)-1-(hydroxymethyl)ethyl]carbamate
N-Boc-serin-(O-t-butyldimethylsilyl)-ol
O-t-butyldimethylsilyl-N-[(1,1-dimethylethoxy)carbonyl]-L-serinol
MFCD03093881
(R)-(+)-N-(tert-Butoxycarbonyl)-O-(tert-butyldimethylsilyl)serinol
(R)-[1-(tert-butyl-dimethyl-silanyloxymethyl)-2-hydroxy-ethyl]-carbamic acid tert-butyl ester
1,1-dimethylethyl [(1R)-2-{[(1,1-dimethylethyl)(dimethyl)silyl]oxy}-1-(hydroxymethyl)ethyl]carbamate
tert-butyl (R)-1-(tert-butyldimethylsilyloxy)-3-hydroxypropan-2-yl carbamate
(R)-tert-butyl 1-(tert-butyldimethylsilyloxy)-3-hydroxypropan-2-ylcarbamate
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