(S)-xyl-BINAP

Modify Date: 2025-08-26 18:04:24

(S)-xyl-BINAP Structure
(S)-xyl-BINAP structure
 Common Name (S)-xyl-BINAP
CAS Number 137219-86-4 Molecular Weight 734.885
Density N/A Boiling Point 825.3±65.0 °C at 760 mmHg
Molecular Formula C52H48P2 Melting Point 187-191ºC
MSDS Chinese USA Flash Point 485.3±40.6 °C

 Names

Name (R)-(+)-2,2-Bis(di-3,5-Xylylphosphino)-1,1-Binaphthyl
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 825.3±65.0 °C at 760 mmHg
Melting Point 187-191ºC
Molecular Formula C52H48P2
Molecular Weight 734.885
Flash Point 485.3±40.6 °C
Exact Mass 734.323120
PSA 27.18000
LogP 17.06
Vapour Pressure 0.0±2.9 mmHg at 25°C

 Safety Information

Hazard Codes Xi
RIDADR NONH for all modes of transport

 Synthetic Route

2,2'-bis[di-(3,5-dimethylphenyl)phosphoryl]-1,1'-binaphthyl structure

2,2'-bis[di-(3,...

CAS#:137219-84-2

~96%

(S)-xyl-BINAP Structure

(S)-xyl-BINAP

CAS#:137219-86-4

Literature: Wu, Hai-Chen; Yu, Jin-Quan; Spencer, Jonathan B. Organic Letters, 2004 , vol. 6, # 25 p. 4675 - 4678
bis(3,5-dimethylphenyl)bromophosphine structure

bis(3,5-dimethy...

CAS#:1342819-37-7

(+/-)-2,2-Dibromo-1,1-Binaphthyl structure

(+/-)-2,2-Dibro...

CAS#:74866-28-7

~76%

(S)-xyl-BINAP Structure

(S)-xyl-BINAP

CAS#:137219-86-4

Literature: Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831
bis(3,5-dimethylphenyl)bromophosphine structure

bis(3,5-dimethy...

CAS#:1342819-37-7

(R)-trifluoro-methanesulfonic acid 2’-trifluoromethanesulfonyloxy [1,1’]binapthalenyl-2-yl ester structure

(R)-trifluoro-m...

CAS#:141807-44-5

~47%

(S)-xyl-BINAP Structure

(S)-xyl-BINAP

CAS#:137219-86-4

Literature: Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831
3,5-dimethylphenylmagnesium bromide structure

3,5-dimethylphe...

CAS#:34696-73-6

~%

(S)-xyl-BINAP Structure

(S)-xyl-BINAP

CAS#:137219-86-4

Literature: Organic Letters, , vol. 6, # 25 p. 4675 - 4678
Phosphinic chloride, P,P-bis(3,5-dimethylphenyl)- structure

Phosphinic chlo...

CAS#:137219-83-1

~%

(S)-xyl-BINAP Structure

(S)-xyl-BINAP

CAS#:137219-86-4

Literature: Organic Letters, , vol. 6, # 25 p. 4675 - 4678
Bis(3,5-dimethylphenyl)chlorophosphine structure

Bis(3,5-dimethy...

CAS#:74289-57-9

~%

(S)-xyl-BINAP Structure

(S)-xyl-BINAP

CAS#:137219-86-4

Literature: Organic Letters, , vol. 6, # 25 p. 4675 - 4678
[bis-(3,5-dimethylphenyl)](diethylamino)phosphine structure

[bis-(3,5-dimet...

CAS#:194149-25-2

~%

(S)-xyl-BINAP Structure

(S)-xyl-BINAP

CAS#:137219-86-4

Literature: Organic Letters, , vol. 6, # 25 p. 4675 - 4678

 Synonyms

(S)-xylyl-BINAP
Phosphine, 1,1'-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(3,5-dimethylphenyl)-
(S)-xyl-BINAP
(R)-DM-BINAP
1,1'-Binaphthalene-2,2'-diylbis[bis(3,5-dimethylphenyl)phosphine]
(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
MFCD01630821
(R)-(+)-2,2′-Bis(di-3,5-xylylphosphino)-1,1′-binaphthyl
(R)-(+)-XylBINAP
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