fluorophosphoric acid

Modify Date: 2024-01-03 20:09:17

fluorophosphoric acid Structure
fluorophosphoric acid structure
Common Name fluorophosphoric acid
CAS Number 13537-32-1 Molecular Weight 99.98620
Density 1.83 g/mL at 25 °C Boiling Point N/A
Molecular Formula FH2O3P Melting Point N/A
MSDS Chinese Flash Point N/A
Symbol GHS05 GHS06
GHS05, GHS06
Signal Word Danger

 Names

Name fluorophosphoric acid
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.83 g/mL at 25 °C
Molecular Formula FH2O3P
Molecular Weight 99.98620
Exact Mass 99.97260
PSA 67.34000
LogP 0.04860

 MSDS

Name: Fluorophosphoric Acid 70% Material Safety Data Sheet
Synonym: Monofluorophosphoric Acid; Phosphorofluoridic Acid
CAS: 13537-32-1
Section 1 - Chemical Product MSDS Name:Fluorophosphoric Acid 70% Material Safety Data Sheet
Synonym:Monofluorophosphoric Acid; Phosphorofluoridic Acid

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
13537-32-1 Fluorophosphoric Acid 70% unlisted
Hazard Symbols: T
Risk Phrases: 23/24/25 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Causes burns.Hygroscopic (absorbs moisture from the air).Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May cause systemic effects.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use dry chemical. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Use and store under nitrogen. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 13537-32-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: pungent odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: None.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: 1.8300g/cm3
Molecular Formula: H2PO3F
Molecular Weight: 99.99

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, moisture, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, strong bases, strong oxidizing agents.
Hazardous Decomposition Products:
Phosphine, irritating and toxic fumes and gases, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13537-32-1: TE5000000 LD50/LC50:
Not available.
Carcinogenicity:
Fluorophosphoric Acid - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: FLUOROPHOSPHORIC ACID, ANHYDROUS
Hazard Class: 8
UN Number: 1776
Packing Group: II
IMO
Shipping Name: FLUOROPHOSPHORIC ACID, ANHYDROUS
Hazard Class: 8
UN Number: 1776
Packing Group: II
RID/ADR
Shipping Name: FLUOROPHOSPHORIC ACID, ANHYDROUS
Hazard Class: 8
UN Number: 1776
Packing group: II

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13537-32-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13537-32-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13537-32-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TE5000000
CHEMICAL NAME :
Phosphorofluoridic acid
CAS REGISTRY NUMBER :
13537-32-1
LAST UPDATED :
199503
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
F-H2-O3-P
MOLECULAR WEIGHT :
99.99
WISWESSER LINE NOTATION :
QPQO&F

 Safety Information

Symbol GHS05 GHS06
GHS05, GHS06
Signal Word Danger
Hazard Statements H301 + H311 + H331-H314
Precautionary Statements P261-P280-P301 + P310-P305 + P351 + P338-P310
Hazard Codes T,C
Risk Phrases R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . R34:Causes burns.
Safety Phrases S26-S27-S36/37/39-S45
RIDADR UN 1776 8/PG 2
RTECS TE5000000
Packaging Group II
Hazard Class 8

 Synthetic Route

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CAS#:13537-32-1

Literature: Journal of the American Chemical Society, , vol. 69, p. 1073 - 1076

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CAS#:13537-32-1

Literature: RSC Advances, , vol. 3, # 37 p. 16359 - 16364

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CAS#:13537-32-1

Literature: Ber., , vol. 64, p. 2772 - 2783 Z. Anorg. Chem., , vol. 214, p. 44 - 54 F: SVol.1, 54, page 207 - 209

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CAS#:13537-32-1

Literature: Z. anorg. allg. Chem., , vol. 289, p. 66 - 79 P: MVol.C, 174, page 399 - 403

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CAS#:13537-32-1

Literature: Chemische Berichte, , vol. 96, p. 1328 - 1334

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CAS#:13537-32-1

Literature: US2423895 , ; C. A., , p. 1711

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Literature: US2423895 , ; C. A., , p. 1711

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Detail
Literature: Journal of the Electrochemical Society, , vol. 152, # 12 p. A2327-A2334

 Synonyms

fluorophosphonic acid
FLUOROPHOSPHORIC ACID
MFCD00011334