2-Bromo-2-butene

Modify Date: 2024-01-06 09:23:51

2-Bromo-2-butene Structure
2-Bromo-2-butene structure
Common Name 2-Bromo-2-butene
CAS Number 13294-71-8 Molecular Weight 135.00200
Density 1.32 Boiling Point 82-90ºC(740 torr)
Molecular Formula C4H7Br Melting Point -115.07°C (estimate)
MSDS USA Flash Point 1.1ºC
Symbol GHS02
GHS02
Signal Word Danger

 Names

Name 2-Bromo-2-butene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.32
Boiling Point 82-90ºC(740 torr)
Melting Point -115.07°C (estimate)
Molecular Formula C4H7Br
Molecular Weight 135.00200
Flash Point 1.1ºC
Exact Mass 133.97300
LogP 2.30500
Vapour Pressure 55.2mmHg at 25°C
Index of Refraction n20/D 1.461(lit.)
Storage condition 2-8°C
Water Solubility Not miscible or difficult to mix in water (664 mg/L 25 EST).

 Safety Information

Symbol GHS02
GHS02
Signal Word Danger
Hazard Statements H225
Precautionary Statements P210
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Highlyflammable;
Risk Phrases R11
Safety Phrases S16
RIDADR UN 1993 3
WGK Germany 3
Packaging Group II

 Synthetic Route

~93%

2-Bromo-2-butene Structure

2-Bromo-2-butene

CAS#:13294-71-8

Literature: Boulder Scientific Company Patent: US6388151 B1, 2002 ; Location in patent: Page column 1-2 ;

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2-Bromo-2-butene Structure

2-Bromo-2-butene

CAS#:13294-71-8

Literature: Whitesides,G.M. et al. Journal of the American Chemical Society, 1971 , vol. 93, # 6 p. 1379 - 1389 Full Text View citing articles Show Details Gmelin Handbook: Ag: MVol.B5, 1.1.2, page 6 - 8

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Detail
Literature: Journal of the American Chemical Society, , vol. 61, p. 1711,1712

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2-Bromo-2-butene Structure

2-Bromo-2-butene

CAS#:13294-71-8

Literature: Journal of the Society of Chemical Industry, London, , vol. 43, p. 309 T Chem. Zentralbl., , vol. 96, # I p. 43

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2-Bromo-2-butene Structure

2-Bromo-2-butene

CAS#:13294-71-8

Literature: Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, , vol. 36, p. 972 Chem. Zentralbl., , vol. 76, # I p. 145

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2-Bromo-2-butene Structure

2-Bromo-2-butene

CAS#:13294-71-8

Literature: Zhurnal Obshchei Khimii, , vol. 4, p. 1460,1462 Chem. Zentralbl., , vol. 107, # II p. 1331

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2-Bromo-2-butene Structure

2-Bromo-2-butene

CAS#:13294-71-8

Literature: Zhurnal Obshchei Khimii, , vol. 17, p. 971 Chem.Abstr., , p. 4592

 Articles2

More Articles
A new process for the regiocontrolled synthesis of substituted catechols and other 1, 2-dioxygenated aromatics: conjugate addition of vinyl-, aryl-, and heteroarylcopper reagents to cyclobutenediones followed by thermal rearrangement. Gurski A and Liebskind LS.

J. Am. Chem. Soc. 115(14) , 6101-8, (1993)

Novel synthesis and structures of tris-annelated benzene donors for the electron-density elucidation of the classical Mills-Nixon effect. Rathore R, et al.

J. Am. Chem. Soc. 120(24) , 6012-18, (1998)

 Synonyms

3-bromo-2-butene
2-bromo-2-buten
TRANS-2-BROMO-2-BUTENE
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EINECS 236-316-2
2-BroMo-2-butene&2-Bromobut-2-ene
2-BROMO-TRANS-2-BUTENE
Bromobutenecistrans
2-Butene,2-bromo
MFCD00000141
1-Methyl-1-propenyl Bromide