dibromo(1,5-cyclooctadiene)platinum(ii)

Modify Date: 2024-01-21 19:01:16

dibromo(1,5-cyclooctadiene)platinum(ii) Structure
dibromo(1,5-cyclooctadiene)platinum(ii) structure
Common Name dibromo(1,5-cyclooctadiene)platinum(ii)
CAS Number 12145-48-1 Molecular Weight 463.06700
Density N/A Boiling Point 153.5ºC at 760 mmHg
Molecular Formula C8H12Br2Pt Melting Point N/A
MSDS N/A Flash Point 31.7ºC

 Names

Name (1Z,5Z)-cycloocta-1,5-diene,dibromoplatinum
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 153.5ºC at 760 mmHg
Molecular Formula C8H12Br2Pt
Molecular Weight 463.06700
Flash Point 31.7ºC
Exact Mass 460.89500
LogP 4.36150
Vapour Pressure 4.25mmHg at 25°C
Water Solubility Insoluble in water.

 MSDS


Section 1: Product Identification
Chemical Name:Dibromo(1,5-cyclooctadiene)platinum (II), 98%
CAS Registry Number:12145-48-1
Formula:Pt(1,5-C8H12)Br2
EINECS Number:None
Chemical Family:organometallic complexes
Synonym:(1,5-cyclooctadiene)platinum dibromide

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound12145-48-1100%1mg/m3(as-Pt)no data

Section 3: Hazards Identification
Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, inhalation, skin
Eye Contact:Causes mild to moderate irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds may lead to wheezing, coughing,
Acute Health Affects:
and running of the nose. Skin exposure may lead to dermatitis.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:To minimize exposure, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:To minimize exposure, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white to pale yellow pwdr.
Molecular Weight:463.09
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents, halogens and active metals
Decomposition Products:carbon dioxide, carbon monoxide, hydrogen bromide, organic fumes and platinum salts.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Not regulated by Title 313.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26
WGK Germany 3

 Synthetic Route

~%

dibromo(1,5-cyclooctadiene)platinum(ii) Structure

dibromo(1,5-cyc...

CAS#:12145-48-1

Literature: Polyhedron, , vol. 7, p. 1925 - 1930

 Precursor & DownStream

Precursor  1

DownStream  0

 Synonyms

dibromo(1,5-cyclooctadiene)platinum(ii)
MFCD00058724