Lead titanate

Synonym:Lead titanium oxide,C.I. Pigment yellow

---

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound12060-00-3100%0.05mg/m3 (as Pb)0.05mg/m3 (as Pb)

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Section 3: Hazards Identification
Very toxic if swallowed. Harmful by inhalation. Possible risk of impaired fertility and harm to the unborn child.
Emergency Overview:
Danger of cumulative effects. May cause cancer.
Primary Routes of Exposure:Ingestion, skin, inhalation of dust.
Eye Contact:May cause slight to mild irritation of the skin.
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:Harmful by inhalation. Large dust exposure may cause seizures, coma, and cardio respiratory arrest.
Very toxic if swallowed. Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea,
Ingestion:
weakness, and convulsions.
Very toxic if swallowed. Harmful by inhalation. May be irritating to skin, eyes and respiratory tract. Possible risk
Acute Health Affects:
of harm to the unborn child. Danger of cumulative effects.
Possible risk of impaired fertility. May cause cancer. The chronic effects include diarrhea, loss of appetite,
Chronic Health Affects:insomnia, weakness, muscle pain, headache, dizziness, anemia. The subject of chronic lead poisoning can
not be adequately addressed in this document.
NTP:No
IARC:Yes
OSHA:Yes

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:none required
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic lead oxide dust.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.

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SECTION 7: Handling and Storage
Handling and Storage:Store material in a tightly sealed bottle.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:If possible, handle the material in an efficient fume hood.
In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a
Respirator:
Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form:-325 mesh yellow pwdr.
Molecular Weight:303.09
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:7.5
Odor:none
Solubility in Water:insoluble

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SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:none
Decomposition Products:Toxic fume of lead oxides

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SECTION 11: Toxicological Information
RTECS Data:Oral (rat); LD50: >12 gm/kg. Intraperitoneal (rat); LD50: 2 gm/kg.
Carcinogenic Effects:carcinogen (as Pb)
Mutagenic Effects:no data
Tetratogenic Effects:no data

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SECTION 12: Ecological Information
Avoid release to groundwater or waterways. Very toxic to aquatic organisms. May cause long-term adverse
Ecological Information:
effects.

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SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR):Toxic solid, Inorganic, N.O.S.
Hazard Class (CFR):6.1
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 3288
Shipping Name (IATA):Toxic solid, Inorganic, N.O.S.
Hazard Class (IATA):6.1
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 3288

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SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound: see category code N420 for reporting
Second Ingredient:none

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SECTION 16 - ADDITIONAL INFORMATION
N/A

MOLECULAR FORMULA :

O3-Ti.Pb

MOLECULAR WEIGHT :

303.09

WISWESSER LINE NOTATION :

PB TI-O3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

>12 gm/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

IMSUAI Industrial Medicine and Surgery. (Northbrook, IL) V.18-42, 1949-73. For publisher information, see IOHSA5. Volume(issue)/page/year: 31,302,1962

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

2 gm/kg

REFERENCE :

IMSUAI Industrial Medicine and Surgery. (Northbrook, IL) V.18-42, 1949-73. For publisher information, see IOHSA5. Volume(issue)/page/year: 31,302,1962 *** REVIEWS *** ACGIH TLV-TWA 0.05 mg(Pb)/m3; animal carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.05 mg(Pb)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.15 mg(Pb)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.1 mg(Pb)/m3 JAN 1993 OEL-BELGIUM:TWA 0.15 mg(Pb)/m3 JAN 1993 OEL-DENMARK:TWA 0.1 mg(Pb)/m3 JAN 1993 OEL-FINLAND:TWA 0.1 mg(Pb)/m3 JAN 1993 OEL-FRANCE:TWA 0.15 mg(Pb)/m3 JAN 1993 OEL-GERMANY:TWA 0.1 mg(Pb)/m3 JAN 1993 OEL-HUNGARY:STEL 0.04 mg(Pb)/m3;Carcinogen JAN 1993 OEL-THE PHILIPPINES:TWA 0.15 mg(Pb)/m3 JAN 1993 OEL-RUSSIA:STEL 0.005 ppm (0.01 mg(Pb)/m3) JAN 1993 OEL-SWEDEN:TWA 0.05 mg(Pb)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 0.1 mg(Pb)/m3 (total dust) JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Pb)/m3 JAN 1993 OEL-THAILAND:TWA 0.2 mg(Pb)/m3 JAN 1993 OEL-TURKEY:TWA 0.2 mg(Pb)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.15 mg(Pb)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO LEAD, INORGANIC-air:10H TWA <0.1 mg(Pb)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992