BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)(2',4',6'-TRIISOPROPYL-3,6-DIMETHOXY-[1,1'-BIPHENYL]-2-YL)PHOSPHINE structure
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Common Name | BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)(2',4',6'-TRIISOPROPYL-3,6-DIMETHOXY-[1,1'-BIPHENYL]-2-YL)PHOSPHINE | ||
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CAS Number | 1160861-60-8 | Molecular Weight | 796.66400 | |
Density | N/A | Boiling Point | N/A | |
Molecular Formula | C39H37F12O2P | Melting Point | 186-190 °C | |
MSDS | Chinese USA | Flash Point | N/A |
Name | bis[3,5-bis(trifluoromethyl)phenyl]-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane |
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Synonym | More Synonyms |
Melting Point | 186-190 °C |
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Molecular Formula | C39H37F12O2P |
Molecular Weight | 796.66400 |
Exact Mass | 796.23400 |
PSA | 32.05000 |
LogP | 12.57440 |
Hazard Codes | Xi |
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RIDADR | NONH for all modes of transport |
~67% BIS(3,5-BIS(TRI... CAS#:1160861-60-8 |
Literature: Hicks, Jacqueline D.; Hyde, Alan M.; Cuezva, Alberto Martinez; Buchwald, Stephen L. Journal of the American Chemical Society, 2009 , vol. 131, # 46 p. 16720 - 16734 |
Precursor 2 | |
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DownStream 0 |
Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.
Acc. Chem. Res. 41 , 1461, (2008) The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia... |
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Biaryl phosphane ligands in palladium-catalyzed amination.
Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008) Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr... |
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Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.
Chem. Sci. 2 , 27, (2011) Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th... |
MFCD17015286 |