[chloro(methyl)phosphoryl]methane

Modify Date: 2024-01-02 12:54:19

[chloro(methyl)phosphoryl]methane Structure
[chloro(methyl)phosphoryl]methane structure
Common Name [chloro(methyl)phosphoryl]methane
CAS Number 1111-92-8 Molecular Weight 112.49500
Density 1.158 g/cm3 Boiling Point 204ºC at 760 mmHg
Molecular Formula C2H6ClOP Melting Point 65-71ºC(lit.)
MSDS Chinese USA Flash Point 77.2ºC
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name dimethylphosphinic chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.158 g/cm3
Boiling Point 204ºC at 760 mmHg
Melting Point 65-71ºC(lit.)
Molecular Formula C2H6ClOP
Molecular Weight 112.49500
Flash Point 77.2ºC
Exact Mass 111.98400
PSA 26.88000
LogP 1.76290
Vapour Pressure 0.385mmHg at 25°C
Index of Refraction 1.39

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C: Corrosive;
Risk Phrases R34
Safety Phrases 26-27-28-36/37/39-45
RIDADR UN 3261 8
WGK Germany 3
Packaging Group II
HS Code 2903199000

 Synthetic Route

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[chloro(methyl)phosphoryl]methane Structure

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CAS#:1111-92-8

Literature: Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 57 Chem.Abstr., , p. 5739

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[chloro(methyl)phosphoryl]methane Structure

[chloro(methyl)...

CAS#:1111-92-8

Literature: Ramage, Robert; Atrash, Butrus; Hopton, David; Parrot, Maxwell J. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1217 - 1226

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[chloro(methyl)phosphoryl]methane Structure

[chloro(methyl)...

CAS#:1111-92-8

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 55, # 12 p. 2805 - 2806,2497 - 2498

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[chloro(methyl)phosphoryl]methane Structure

[chloro(methyl)...

CAS#:1111-92-8

Literature: Tetrahedron Letters, , vol. 27, # 35 p. 4181 - 4184

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[chloro(methyl)phosphoryl]methane Structure

[chloro(methyl)...

CAS#:1111-92-8

Literature: Phosphorus and Sulfur and the Related Elements, , vol. 13, p. 69 - 78

 Customs

HS Code 2903199000
Summary 2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

 Articles3

More Articles
Pyridinolysis of Diethyl Phosphinic Chloride in Acetonitrile. Dey NK, et al.

Bull. Korean Chem. Soc. 32(2) , 709-12, (2011)

Kinetics and mechanism of the aminolysis of dimethyl and methyl phenyl phosphinic chlorides with anilines. Dey NK, et al.

J. Phys. Org. Chem. 22(5) , 425-30, (2009)

Dialkylethynylphosphine oxides; synthesis and reactions. Hagens W, et al.

Rec. Trav. Chim. 88(1) , 71-85, (1969)

 Synonyms

[chloro(methyl)phosphoryl]methane
EINECS 214-187-3
MFCD00002078