2-Bromo-6-chloro-4-(trifluoromethyl)aniline

Modify Date: 2024-01-02 11:27:56

2-Bromo-6-chloro-4-(trifluoromethyl)aniline Structure
2-Bromo-6-chloro-4-(trifluoromethyl)aniline structure
Common Name 2-Bromo-6-chloro-4-(trifluoromethyl)aniline
CAS Number 109919-26-8 Molecular Weight 274.466
Density 1.8±0.1 g/cm3 Boiling Point 224.8±40.0 °C at 760 mmHg
Molecular Formula C7H4BrClF3N Melting Point 27-30 °C(lit.)
MSDS USA Flash Point 89.7±27.3 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 2-bromo-6-chloro-4-(trifluoromethyl)aniline
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.8±0.1 g/cm3
Boiling Point 224.8±40.0 °C at 760 mmHg
Melting Point 27-30 °C(lit.)
Molecular Formula C7H4BrClF3N
Molecular Weight 274.466
Flash Point 89.7±27.3 °C
Exact Mass 272.916779
PSA 26.02000
LogP 4.02
Vapour Pressure 0.1±0.4 mmHg at 25°C
Index of Refraction 1.539
Storage condition Room temperature.

 MSDS

Name: 4-Amino-3-bromo-5-chlorobenzotrifluoride Material Safety Data Sheet
Synonym: 2-Bromo-6-chloro-4-trifluoromethylanilin
CAS: 109919-26-8
Section 1 - Chemical Product MSDS Name:4-Amino-3-bromo-5-chlorobenzotrifluoride Material Safety Data Sheet
Synonym:2-Bromo-6-chloro-4-trifluoromethylanilin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
109919-26-8 4-Amino-3-bromo-5-chlorobenzotrifluori unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use carbon dioxide, dry chemical, or water fog.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 109919-26-8: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 71-72 deg C @ 0.25
Freezing/Melting Point: 29-32 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H4BrClF3N
Molecular Weight: 274.3869

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas, hydrogen bromide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 109919-26-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Amino-3-bromo-5-chlorobenzotrifluoride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 109919-26-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 109919-26-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109919-26-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn:Harmful;
Risk Phrases R20/21/22;R36/37/38
Safety Phrases S26-S36
RIDADR 2811
WGK Germany 3
Packaging Group III
Hazard Class 6.1
HS Code 2921420090

 Precursor & DownStream

Precursor  0

DownStream  1

 Customs

HS Code 2921420090
Summary HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Synonyms

2-bromo-6-chloro-4-trifluoromethylaniline
Benzenamine, 2-bromo-6-chloro-4-(trifluoromethyl)-
2-Bromo-6-chloro-4-(trifluoromethyl)aniline
4-Amino-3-bromo-5-chlorobenzotrifluoride
MFCD00042180