(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one

Modify Date: 2024-01-04 19:31:15

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure
(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one structure
 Common Name (4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one
CAS Number 108906-56-5 Molecular Weight 362.37200
Density 1.48g/cm3 Boiling Point 641.3ºC at 760 mmHg
Molecular Formula C16H26O9 Melting Point N/A
MSDS N/A Flash Point 234ºC

 Names

Name (4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.48g/cm3
Boiling Point 641.3ºC at 760 mmHg
Molecular Formula C16H26O9
Molecular Weight 362.37200
Flash Point 234ºC
Exact Mass 362.15800
PSA 145.91000
Vapour Pressure 3.77E-19mmHg at 25°C
Index of Refraction 1.592

 Synthetic Route

(4R,4aS,6S,7S,7aS)-7-((benzyloxy)methyl)-4-methyl-6-(((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)hexahydrocyclopenta[c]pyran-3(1H)-one structure

(4R,4aS,6S,7S,7...

CAS#:500102-44-3

~83%

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure

(4R,4aS,6S,7S,7...

CAS#:108906-56-5

Literature: Takacs, James M.; Vayalakkada, Suresh; Mehrman, Steven J.; Kingsbury, Celia L. Tetrahedron Letters, 2002 , vol. 43, # 46 p. 8417 - 8420
2 3 4 6-tetra-o-benzyl-alpha-d-glucopyr& structure

2 3 4 6-tetra-o...

CAS#:74808-09-6

~%

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure

(4R,4aS,6S,7S,7...

CAS#:108906-56-5

Literature: Takacs, James M.; Vayalakkada, Suresh; Mehrman, Steven J.; Kingsbury, Celia L. Tetrahedron Letters, 2002 , vol. 43, # 46 p. 8417 - 8420
N/A structure

N/A

CAS#:500102-37-4

~%

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure

(4R,4aS,6S,7S,7...

CAS#:108906-56-5

Literature: Takacs, James M.; Vayalakkada, Suresh; Mehrman, Steven J.; Kingsbury, Celia L. Tetrahedron Letters, 2002 , vol. 43, # 46 p. 8417 - 8420
N/A structure

N/A

CAS#:500102-43-2

~%

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure

(4R,4aS,6S,7S,7...

CAS#:108906-56-5

Literature: Takacs, James M.; Vayalakkada, Suresh; Mehrman, Steven J.; Kingsbury, Celia L. Tetrahedron Letters, 2002 , vol. 43, # 46 p. 8417 - 8420
N/A structure

N/A

CAS#:500102-35-2

~%

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure

(4R,4aS,6S,7S,7...

CAS#:108906-56-5

Literature: Takacs, James M.; Vayalakkada, Suresh; Mehrman, Steven J.; Kingsbury, Celia L. Tetrahedron Letters, 2002 , vol. 43, # 46 p. 8417 - 8420
methyl (E)-4-((4S,5S)-5-((E)-buta-1,3-dien-1-yl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl)but-2-enoate structure

methyl (E)-4-((...

CAS#:500102-38-5

~%

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure

(4R,4aS,6S,7S,7...

CAS#:108906-56-5

Literature: Takacs, James M.; Vayalakkada, Suresh; Mehrman, Steven J.; Kingsbury, Celia L. Tetrahedron Letters, 2002 , vol. 43, # 46 p. 8417 - 8420
N/A structure

N/A

CAS#:500102-42-1

~%

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure

(4R,4aS,6S,7S,7...

CAS#:108906-56-5

Literature: Takacs, James M.; Vayalakkada, Suresh; Mehrman, Steven J.; Kingsbury, Celia L. Tetrahedron Letters, 2002 , vol. 43, # 46 p. 8417 - 8420
(4R,4aS,6S,7S,7aS)-7-((benzyloxy)methyl)-6-((4-methoxybenzyl)oxy)-4-methylhexahydrocyclopenta[c]pyran-3(1H)-one structure

(4R,4aS,6S,7S,7...

CAS#:500102-45-4

~%

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure

(4R,4aS,6S,7S,7...

CAS#:108906-56-5

Literature: Takacs, James M.; Vayalakkada, Suresh; Mehrman, Steven J.; Kingsbury, Celia L. Tetrahedron Letters, 2002 , vol. 43, # 46 p. 8417 - 8420

 Precursor & DownStream

Precursor  1

DownStream  0

 Synonyms

(-)-Gibboside
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Chemsrc provides CAS#:108906-56-5 MSDS, density, melting point, boiling point, structure, etc. Its name is (4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one>> amp version: (4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one

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