Tetrahedron letters

Iron-catalyzed enediene carbocyclizations. The total synthesis of (−)-gibboside

…, S Vayalakkada, SJ Mehrman, CL Kingsbury

Index: Takacs, James M.; Vayalakkada, Suresh; Mehrman, Steven J.; Kingsbury, Celia L. Tetrahedron Letters, 2002 , vol. 43, # 46 p. 8417 - 8420

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Citation Number: 9

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The first total synthesis of (−)-gibboside is reported. The route features a novel iron-catalyzed carbocyclization as the key step for the construction of the cis,trans,cis-tetrasubstituted cyclopentane core. ... The total synthesis of (−)-gibboside via a route that features the diastereoselective ...

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(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure

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(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one Structure

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