Sodium bis(trimethylsilyl)amide

Modify Date: 2024-01-02 17:55:30

Sodium bis(trimethylsilyl)amide Structure
Sodium bis(trimethylsilyl)amide structure
Common Name Sodium bis(trimethylsilyl)amide
CAS Number 1070-89-9 Molecular Weight 183.375
Density 0.904 g/mL at 25 °C Boiling Point 67°C
Molecular Formula C6H18NNaSi2 Melting Point 171-175 °C(lit.)
MSDS Chinese Flash Point 43 °F
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

 Names

Name Sodium bis(trimethylsilyl)amide
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.904 g/mL at 25 °C
Boiling Point 67°C
Melting Point 171-175 °C(lit.)
Molecular Formula C6H18NNaSi2
Molecular Weight 183.375
Flash Point 43 °F
Exact Mass 183.087540
PSA 3.24000
LogP 2.42250
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger
Hazard Statements H225-H314
Supplemental HS May form explosive peroxides., Reacts violently with water.
Precautionary Statements P210-P280-P305 + P351 + P338-P310
Hazard Codes F:Flammable;C:Corrosive;
Risk Phrases R14/15;R34
Safety Phrases S26-S45-S62-S36/37/39-S33-S16-S43-S8
RIDADR UN 3263 8/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 4.3
HS Code 2931900090

 Synthetic Route

~85%

Sodium bis(trimethylsilyl)amide Structure

Sodium bis(trim...

CAS#:1070-89-9

Literature: Mansell, Stephen M.; Perandones, Bernabe Fernandez; Arnold, Polly L. Journal of Organometallic Chemistry, 2010 , vol. 695, # 25-26 p. 2814 - 2821

~99%

Sodium bis(trimethylsilyl)amide Structure

Sodium bis(trim...

CAS#:1070-89-9

Literature: Wiberg, Nils; Bayer, Heiner; Vasisht, Sham Kumar; Meyers, Rene Chemische Berichte, 1980 , vol. 113, # 9 p. 2916 - 2927

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles27

More Articles
Effect of concentration of trimethylchlorosilane (TMCS) and hexamethyldisilazane (HMDZ) silylating agents on surface free energy of silica aerogels.

J. Colloid. Interface Sci. 356(1) , 298-302, (2011)

The surface free energy of a solid determines its surface and interfacial behavior in processes like wetting and adhesion which is crucial for silica aerogels in case of organic liquid absorption and ...

Regulation of mitochondrial ceramide distribution by members of the BCL-2 family.

J. Lipid Res. 56 , 1501-10, (2015)

Apoptosis is an intricately regulated cellular process that proceeds through different cell type- and signal-dependent pathways. In the mitochondrial apoptotic program, mitochondrial outer membrane pe...

A facile two-step dipping process based on two silica systems for a superhydrophobic surface.

Chem. Commun. (Camb.) 47(38) , 10761-3, (2011)

A silica microsphere suspension and a silica sol are employed in a two-step dipping process for the preparation of a superhydrophobic surface. It's not only a facile way to achieve the lotus effect, b...

 Synonyms

Sodium 1,1,1,3,3,3-hexamethyldisilazan-2-ide
MFCD00009835
NaHMDS (contains 2-Methyl-2-butene)
EINECS 213-983-8
NaHMDS
sodium,bis(trimethylsilyl)azanide
Sodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene)
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, sodium salt (1:1)
Sodium Hexamethyldisilazide (contains 2-Methyl-2-butene)
Sodium Bis(Trimethylsilyl)Amide
Hexamethyldisilazane Sodium Salt (contains 2-Methyl-2-butene)
Sodium bis(trimethyls
Hexamethyldisilazane Sodium