tert-Butyl peroxyacetate

Modify Date: 2024-01-02 20:14:52

tert-Butyl peroxyacetate Structure
tert-Butyl peroxyacetate structure
Common Name tert-Butyl peroxyacetate
CAS Number 107-71-1 Molecular Weight 132.15800
Density 0.828 g/mL at 25 °C Boiling Point 122.7ºC at 760 mmHg
Molecular Formula C6H12O3 Melting Point -20 °C
MSDS Chinese Flash Point 99 °F
Symbol GHS02 GHS06 GHS08
GHS02, GHS06, GHS08
Signal Word Danger

 Names

Name tert-Butyl ethaneperoxoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.828 g/mL at 25 °C
Boiling Point 122.7ºC at 760 mmHg
Melting Point -20 °C
Molecular Formula C6H12O3
Molecular Weight 132.15800
Flash Point 99 °F
Exact Mass 132.07900
PSA 35.53000
LogP 1.27960
Vapour Pressure 13.8mmHg at 25°C
Index of Refraction n20/D 1.412

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SD8925000
CHEMICAL NAME :
Peroxyacetic acid, tert-butyl ester
CAS REGISTRY NUMBER :
107-71-1
BEILSTEIN REFERENCE NO. :
1701510
LAST UPDATED :
199701
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C6-H12-O3
MOLECULAR WEIGHT :
132.18
WISWESSER LINE NOTATION :
1X1&1&OOV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Rinsed with water
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 8,25,1958 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
675 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,30,1982
TYPE OF TEST :
LC33 - Lethal Concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
8200 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,30,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
632 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 9,78,1967
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
6000 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 9,78,1967 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1 mg/m3/4H/17W-I
TOXIC EFFECTS :
Behavioral - alteration of operant conditioning Blood - other changes Blood - changes in other cell count (unspecified)
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 10,44,1968 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
DOSE :
1 mg/m3/4H
SEX/DURATION :
male 17 week(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count)
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 10,44,1968 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-GERMANY JAN 1993 OEL-RUSSIA:STEL 0.1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5363 No. of Facilities: 3 (estimated) No. of Industries: 1 No. of Occupations: 8 No. of Employees: 277 (estimated)

 Safety Information

Symbol GHS02 GHS06 GHS08
GHS02, GHS06, GHS08
Signal Word Danger
Hazard Statements H226-H242-H302-H304-H315-H319-H331-H335-H340-H350
Precautionary Statements P201-P210-P280-P304 + P340 + P312-P308 + P313-P370 + P378
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T: Toxic;F: Flammable;O: Oxidizing agent;Xi: Irritant;
Risk Phrases R23/24/25
Safety Phrases S16-S26-S36/37/39-S45-S62-S47-S14-S7-S53-S3/7
RIDADR UN 3103 5.2
WGK Germany 2
RTECS SD8925000
Packaging Group II
Hazard Class 5.2
HS Code 2918300090

 Synthetic Route

 Customs

HS Code 2918300090
Summary 2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Articles1

More Articles

J. Chem. Soc. Perkin Trans. I , 277, (1990)

 Synonyms

tert-butyl ethaneperoxoate
MFCD00048240
tert-Butyl peroxyacetate
tert-Butyl peracetate
EINECS 203-514-5