6-dodecyl(14-crown-4)-6-ethanol diethylphosphate

Modify Date: 2024-01-10 11:18:52

6-dodecyl(14-crown-4)-6-ethanol diethylphosphate Structure
6-dodecyl(14-crown-4)-6-ethanol diethylphosphate structure
Common Name 6-dodecyl(14-crown-4)-6-ethanol diethylphosphate
CAS Number 106868-29-5 Molecular Weight 552.72100
Density N/A Boiling Point N/A
Molecular Formula C28H57O8P Melting Point N/A
MSDS N/A Flash Point -4℃
Symbol GHS02 GHS07 GHS08 GHS09
GHS02, GHS07, GHS08, GHS09
Signal Word Danger

 Names

Name 2-(6-dodecyl-1,4,8,11-tetraoxacyclotetradec-6-yl)ethyl diethyl phosphate
Synonym More Synonyms

 Chemical & Physical Properties

Molecular Formula C28H57O8P
Molecular Weight 552.72100
Flash Point -4℃
Exact Mass 552.37900
PSA 91.49000
LogP 7.34010
Storage condition 2-8°C

 MSDS

Version 1.2
Regulation (EC) No 1907/2006

1 - Product and Company Information

Product NameLITHIUM IONOPHORE VII (10 MG IN 0.1 ML
HEPTANE)

2 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Highly flammable.

3 - Composition/Information on Ingredients

Product NameCAS #EC noAnnex I
Index Number
6-(2-(DIETH.PHOSPH.OXY)ETH.)6-DODE 106868-29-5 NoneNone
CYL-14-CROWN-4 (10MG,SOLUTION)
FormulaC28H57O8P
Molecular Weight 552,7000 AMU

4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.

5 - Fire Fighting Measures

EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
SPECIAL RISKS
Specific Hazard(s): Flammable liquid. Vapor may travel
considerable distance to source of ignition and flash back.
Explosion Hazards: Vapor may travel considerable distance to
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source of ignition and flash back. Container explosion may occur
under fire conditions. Forms explosive mixtures in air.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
SPECIFIC METHOD(S) OF FIRE FIGHTING
Use water spray to cool fire-exposed containers.

6 - Accidental Release Measures

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with an activated carbon adsorbent, take up and place in
closed containers. Transport outdoors. Ventilate area and wash
spill site after material pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Do not breathe vapor. Avoid
contact with eyes, skin, and clothing. Avoid prolonged or
repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Keep away from heat,
sparks, and open flame. Store in a cool dry place.

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Use nonsparking tools. Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Remove and wash contaminated
clothing promptly.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Where risk assessment shows air-purifying respirators
are appropriate use a full-face respirator with multi-purpose
combination (US) or type ABEK (EN 14387) respirator cartridges as
a backup to engineering controls. If the respirator is the sole
means of protection, use a full-face supplied air respirator.
Hand Protection: Rubber gloves.
Eye Protection: Chemical safety goggles.

9 - Physical and Chemical Properties

AppearancePhysical State: Liquid
PropertyValueAt Temperature or Pressure
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pH N/A
BP/BP RangeN/A
MP/MP RangeN/A
Flash PointN/A
FlammabilityN/A
Autoignition TempN/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion LimitsN/A
Vapor PressureN/A
Partition Coefficient N/A
ViscosityN/A
Vapor DensityN/A
Saturated Vapor Conc. N/A
Evaporation RateN/A
Bulk DensityN/A
Decomposition Temp.N/A
Solvent ContentN/A
Water ContentN/A
Surface TensionN/A
ConductivityN/A
Miscellaneous DataN/A
SolubilityN/A

10 - Stability and Reactivity

STABILITY
Materials to Avoid: Oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Phosphorous oxides.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

11 - Toxicological Information

SIGNS AND SYMPTOMS OF EXPOSURE
Narcotic effect. Nausea, dizziness, and headache. Exposure to
large amounts can cause:
ROUTE OF EXPOSURE
Skin Contact: Prolonged or repeated exposure to skin causes
defatting and dermatitis.
Skin Absorption: May be harmful if absorbed through the skin.
Multiple Routes: Vapor or mist is irritating to the eyes, mucous
membranes, and upper respiratory tract. Harmful if inhaled or
swallowed.

12 - Ecological Information

No data available.

13 - Disposal Considerations

SUBSTANCE DISPOSAL
Burn in a chemical incinerator equipped with an afterburner and
scrubber but exert extra care in igniting as this material is
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highly flammable. Observe all federal, state, and local
environmental regulations.

14 - Transport Information

RID/ADR
UN#: 1206
Class: 3
PG: II
Proper Shipping Name: Heptanes solution
IMDG
UN#: 1206
Class: 3
PG: II
Proper Shipping Name: Heptanes solution
Marine Pollutant: No
Severe Marine Pollutant: No
IATA
UN#: 1206
Class: 3
PG: II
Proper Shipping Name: Heptanes solution
Inhalation Packing Group I: No

15 - Regulatory Information

CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: F
Highly Flammable.
R-PHRASES: 11
Highly flammable.
S-PHRASES: 16-23-24/25
Keep away from sources of ignition - no smoking. Do not breathe
vapor. Avoid contact with skin and eyes.
Caution: Substance not yet fully tested (EU).

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS02 GHS07 GHS08 GHS09
GHS02, GHS07, GHS08, GHS09
Signal Word Danger
Hazard Statements H225-H304-H315-H336-H410
Precautionary Statements P210-P261-P273-P301 + P310-P331-P501
Hazard Codes F: Flammable;
Risk Phrases 11
Safety Phrases 16-23-24/25
RIDADR UN 1206 3/PG 2
HS Code 2932999099

 Synthetic Route

~%

6-dodecyl(14-crown-4)-6-ethanol diethylphosphate Structure

6-dodecyl(14-cr...

CAS#:106868-29-5

Literature: Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1945 - 1952

~%

6-dodecyl(14-crown-4)-6-ethanol diethylphosphate Structure

6-dodecyl(14-cr...

CAS#:106868-29-5

Literature: Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1945 - 1952

~%

6-dodecyl(14-crown-4)-6-ethanol diethylphosphate Structure

6-dodecyl(14-cr...

CAS#:106868-29-5

Literature: Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1945 - 1952

~16%

6-dodecyl(14-crown-4)-6-ethanol diethylphosphate Structure

6-dodecyl(14-cr...

CAS#:106868-29-5

Literature: Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1945 - 1952

 Precursor & DownStream

Precursor  2

DownStream  0

 Customs

HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles1

More Articles
K. Kimura et al.

J. Chem. Soc., Perkin Trans. II , 1945, (1986)

 Synonyms

6-Dodecyl(14-crown-4)-6-ethanol diethyl phosphate
Lithium ionophore VII
6-[2-(Diethylphosphonooxy)ethyl]-6-dodecyl-14-crown-4
diethoxyphosphoryloxyethyl-dodecyl-14-crown-4