Allyl glycidyl ether

Modify Date: 2024-01-02 08:40:39

Allyl glycidyl ether Structure
Allyl glycidyl ether structure
 Common Name Allyl glycidyl ether
CAS Number 106-92-3 Molecular Weight 114.142
Density 1.0±0.1 g/cm3 Boiling Point 153.2±15.0 °C at 760 mmHg
Molecular Formula C6H10O2 Melting Point -100 °C
MSDS Chinese USA Flash Point 57.2±0.0 °C
Symbol GHS02 GHS05 GHS07 GHS08
GHS02, GHS05, GHS07, GHS08		 Signal Word Danger

 Names

Name Allyl glycidyl ether
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 153.2±15.0 °C at 760 mmHg
Melting Point -100 °C
Molecular Formula C6H10O2
Molecular Weight 114.142
Flash Point 57.2±0.0 °C
Exact Mass 114.068077
PSA 21.76000
LogP 0.78
Vapour density 3.9 (vs air)
Vapour Pressure 4.3±0.3 mmHg at 25°C
Index of Refraction 1.444
Stability Stable. Combustible. Incompatible with strong oxidizing agents, acids, bases. May form peroxides in storage if in contact with air.
Water Solubility 50 g/L (20 ºC)

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RR0875000
CHEMICAL NAME :
Oxirane, ((2-propenyloxy)methyl)-
CAS REGISTRY NUMBER :
106-92-3
BEILSTEIN REFERENCE NO. :
0105871
LAST UPDATED :
199712
DATA ITEMS CITED :
57
MOLECULAR FORMULA :
C6-H10-O2
MOLECULAR WEIGHT :
114.16
WISWESSER LINE NOTATION :
T3OTJ B1O2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Behavioral - changes in motor activity (specific assay) Behavioral - ataxia
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
670 ppm/8H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - corneal damage Lungs, Thorax, or Respiration - acute pulmonary edema Gastrointestinal - changes in structure or function of salivary glands
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
390 mg/kg
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Behavioral - ataxia
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
270 ppm/4H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - changes in structure or function of salivary glands
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2550 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
400 ppm/7H/10W-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - emphysema Kidney, Ureter, Bladder - changes in bladder weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
200 ppm/6H/14D-I
TOXIC EFFECTS :
Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
400 mg/kg/8D-I
TOXIC EFFECTS :
Blood - changes in bone marrow (not otherwise specified) Blood - changes in leukocyte (WBC) count Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
50 ppm/6H/14D-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10 ppm/6H/2Y-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Sense Organs and Special Senses (Olfaction) - tumors
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
10 ppm/6H/2Y-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Sense Organs and Special Senses (Olfaction) - tumors
TYPE OF TEST :
Sex chromosome loss and nondisjunction

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Lung
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 249,55,1991 *** REVIEWS *** ACGIH TLV-STEL 47 mg/m3 (10 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 23 mg/m3 (5 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 ppm (22 mg/m3) DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,9,1971 OSHA PEL (Gen Indu):CL 10 ppm (45 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 10 ppm (45 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 10 ppm (45 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 10 ppm (45 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 ppm (22 mg/m3);STEL 10 ppm (44 mg/m3);Skin JAN 1993 OEL-AUSTRIA:TWA 10 ppm (45 mg/m3) JAN 1993 OEL-BELGIUM:TWA 5 ppm (23 mg/m3);STEL 10 ppm (47 mg/m3);Skin JAN 1993 OEL-DENMARK:STEL 5 ppm (22 mg/m3);Skin JAN 1993 OEL-FINLAND:STEL 5 ppm (22 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 5 ppm (22 mg/m3);Skin JAN 1993 OEL-GERMANY:TWA 10 ppm (45 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 5 ppm (22 mg/m3);Skin JAN 1993 OEL-THE PHILIPPINES:TWA 10 ppm (45 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 5 ppm (22 mg/m3);STEL 10 ppm (44 mg/m3);Skin JAN 1993 OEL-THAILAND:TWA 10 ppm (45 mg/m3) JAN 1993 OEL-TURKEY:TWA 10 ppm (45 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 5 ppm (22 mg/m3);STEL 10 ppm;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ALLYL GLYCIDYL ETHER-air:10H TWA 5 ppm;STEL 10 ppm (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 04530 No. of Facilities: 153 (estimated) No. of Industries: 9 No. of Occupations: 24 No. of Employees: 2769 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 04530 No. of Facilities: 23 (estimated) No. of Industries: 6 No. of Occupations: 11 No. of Employees: 2457 (estimated) No. of Female Employees: 29 (estimated)

 Safety Information

Symbol GHS02 GHS05 GHS07 GHS08
GHS02, GHS05, GHS07, GHS08
Signal Word Danger
Hazard Statements H226-H302-H315-H317-H318-H332-H335-H341-H351-H361f-H412
Precautionary Statements P261-P273-P280-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn:Harmful;
Risk Phrases R10;R20/22;R37/38;R40;R41;R43;R52/53;R62;R68
Safety Phrases S24/25-S26-S36/37/39-S61
RIDADR UN 2219 3/PG 3
WGK Germany 3
RTECS RR0875000
Packaging Group III
Hazard Class 3
HS Code 2910900090

 Synthetic Route

Allyl ether structure

Allyl ether

CAS#:557-40-4

~34%

Allyl glycidyl ether Structure

Allyl glycidyl ether

CAS#:106-92-3
Literature: Oguchi, Wataru; Nishi, Makoto; Hetsugi, Yukiharu Patent: US2004/122243 A1, 2004 ; Location in patent: Page 12 ;
2-Propanol,1-chloro-3-(2-propen-1-yloxy)- structure

2-Propanol,1-ch...

CAS#:4638-03-3

~76%

Allyl glycidyl ether Structure

Allyl glycidyl ether

CAS#:106-92-3
Literature: Allakhverdiev; Askerov Russian Journal of Applied Chemistry, 2003 , vol. 76, # 8 p. 1280 - 1283
3-BUTEN-2-OL, 1,1,1-TRIFLUORO-2-(TRIFLUOROMETHYL)- structure

3-BUTEN-2-OL, 1...

CAS#:19701-19-0
Tetrabutylammonium sulfate structure

Tetrabutylammon...

CAS#:2472-88-0
Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8

~63%

Allyl glycidyl ether Structure

Allyl glycidyl ether

CAS#:106-92-3
Literature: Shin-Etsu Chemical Co., Ltd. Patent: EP549335 A1, 1993 ;
Allyl alcohol structure

Allyl alcohol

CAS#:107-18-6
Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8

~%

Allyl glycidyl ether Structure

Allyl glycidyl ether

CAS#:106-92-3
Literature: US2314039 , ;
Peracetic acid structure

Peracetic acid

CAS#:79-21-0
Allyl ether structure

Allyl ether

CAS#:557-40-4

~%

Allyl glycidyl ether Structure

Allyl glycidyl ether

CAS#:106-92-3
Literature: Journal of the American Chemical Society, , vol. 81, p. 3350,3352
Allyl ether structure

Allyl ether

CAS#:557-40-4

~%

diglycidyl ether structure

diglycidyl ether

CAS#:2238-07-5
Allyl glycidyl ether Structure

Allyl glycidyl ether

CAS#:106-92-3
Literature: Journal of Catalysis, , vol. 228, # 1 p. 183 - 191

 Customs

HS Code 2910900090
Summary 2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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 Synonyms

2-[(prop-2-en-1-yloxy)methyl]oxirane
3-allyloxy-1,2-epoxypropane
Glycidyl allyl ether
Allylglycide ether
allyloxymethyloxirane
Ally glycidyl ether
EINECS 203-442-4
UNII:HDC0791894
1-Allyl-2,3-epoxypropane
Sipomer AGE
Allylglycidaether
Ageflex AGE
allyl glycidol
Oxirane, 2-[(2-propen-1-yloxy)methyl]-
M 560
MFCD00005143
ALLYLGLYCIDOLETHER
1-allyloxy-2,3-epoxypropane
Allyl glycidyl ether
ether, allyl glycidyl
2-[(Allyloxy)methyl]oxirane
allyl
Ether, allyl 2,3-epoxypropyl
AGE
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