2-Ethylhexyl acrylate

Modify Date: 2024-01-02 15:47:36

2-Ethylhexyl acrylate Structure
2-Ethylhexyl acrylate structure
 Common Name 2-Ethylhexyl acrylate
CAS Number 103-11-7 Molecular Weight 184.275
Density 0.9±0.1 g/cm3 Boiling Point 216.0±0.0 °C at 760 mmHg
Molecular Formula C11H20O2 Melting Point -90ºC
MSDS Chinese USA Flash Point 79.4±0.0 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name 2-Ethylhexyl acrylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 216.0±0.0 °C at 760 mmHg
Melting Point -90ºC
Molecular Formula C11H20O2
Molecular Weight 184.275
Flash Point 79.4±0.0 °C
Exact Mass 184.146332
PSA 26.30000
LogP 4.33
Vapour density 6.4 (vs air)
Vapour Pressure 0.1±0.4 mmHg at 25°C
Index of Refraction 1.434
Stability Stability Stable, but polymerizes readily, so is usually inhibited with hydroquinone or its monomethyl ether. Susceptible to hydrolysis. Combustible. Incompatible with oxidizing agents.
Water Solubility <0.1 g/100 mL at 22 ºC

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AT0855000
CHEMICAL NAME :
Acrylic acid, 2-ethylhexyl ester
CAS REGISTRY NUMBER :
103-11-7
BEILSTEIN REFERENCE NO. :
1765828
LAST UPDATED :
199710
DATA ITEMS CITED :
31
MOLECULAR FORMULA :
C11-H20-O2
MOLECULAR WEIGHT :
184.31
WISWESSER LINE NOTATION :
4Y2&1OV1U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,372,1986
TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 11/3/1971
TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 4,119,1951
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
AJOPAA American Journal of Ophthalmology. (Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611) Series 3: V.1- 1918- Volume(issue)/page/year: 29,1363,1946
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,372,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6500 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 11/3/1971
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>12 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PJPPAA Polish Journal of Pharmacology and Pharmacy. (ARS Polona, POB 1001, 00-068 Warsaw 1, Poland) V.25- 1973- Volume(issue)/page/year: 32,223,1980
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1670 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. (SPPIF, B.P.22, F-41353 Vineuil, France) V.7- 1946- Volume(issue)/page/year: 36,58,1975
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4400 mg/kg
TOXIC EFFECTS :
Behavioral - excitement
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 26(9),52,1982
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
600 mg/m3
TOXIC EFFECTS :
Behavioral - excitement
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 26(9),52,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1326 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JDREAF Journal of Dental Research. (International Assoc. for Dental Research, 734 15th St., NW, Suite 809, Washington, DC 20005) V.1- 1919- Volume(issue)/page/year: 51,526,1972
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>4 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0520808
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
8480 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 4,119,1951
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
>450 mg/m3
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 56(12),19,1991 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4020 mg/kg/30D-I
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - catalases
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 58(3),16,1993
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1785 mg/kg/26W-I
TOXIC EFFECTS :
Liver - other changes Blood - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 58(3),16,1993
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
103 mg/m3/19W-I
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Endocrine - changes in thyroid weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - catalases
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 26(9),52,1982
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1 mg/m3/24H/17W-C
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 56(12),19,1991 ** TUMORIGENIC DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
187 gm/kg/78W-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Skin and Appendages - tumors Tumorigenic - tumors at site of application
REFERENCE :
JTEHD6 Journal of Toxicology and Environmental Health. (Hemisphere Pub., 1025 Vermont Ave., NW, Washington, DC 20005) V.1- 1975/76- Volume(issue)/page/year: 16,55,1985
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
240 gm/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Skin and Appendages - tumors Tumorigenic - tumors at site of application
REFERENCE :
EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-1079-0262 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 60,475,1994 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 60,475,1994 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 60,475,1994 TOXICOLOGY REVIEW EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 11,141,1975 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82082 No. of Facilities: 1437 (estimated) No. of Industries: 17 No. of Occupations: 24 No. of Employees: 26428 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 82082 No. of Facilities: 592 (estimated) No. of Industries: 10 No. of Occupations: 12 No. of Employees: 11277 (estimated) No. of Female Employees: 2341 (estimated)

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H317-H335-H412
Precautionary Statements P273-P280-P304 + P340 + P312-P333 + P313
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant
Risk Phrases R37/38;R43
Safety Phrases S36/37-S46
RIDADR UN3334 9
WGK Germany 1
RTECS AT0855000
HS Code 29161290

 Synthetic Route

2-Ethylhexanol structure

2-Ethylhexanol

CAS#:104-76-7
acrolein structure

acrolein

CAS#:107-02-8

~%

2-Ethylhexyl acrylate Structure

2-Ethylhexyl ac...

CAS#:103-11-7
Literature: US2003/216587 A1, ; Page/Page column 3-4 ;
2-Ethylhexanol structure

2-Ethylhexanol

CAS#:104-76-7
Acrylic acid structure

Acrylic acid

CAS#:79-10-7

~%

2-Ethylhexyl acrylate Structure

2-Ethylhexyl ac...

CAS#:103-11-7
Literature: US2917538 , ;
N/A structure

N/A

CAS#:500790-28-3

~%

2-Ethylhexyl acrylate Structure

2-Ethylhexyl ac...

CAS#:103-11-7
Literature: Journal of the American Chemical Society, , vol. 67, p. 57
2-Ethylhexanol structure

2-Ethylhexanol

CAS#:104-76-7
Acetylene structure

Acetylene

CAS#:74-86-2

~%

2-Ethylhexyl acrylate Structure

2-Ethylhexyl ac...

CAS#:103-11-7
Literature: US2809976 , ;
2-Ethylhexanol structure

2-Ethylhexanol

CAS#:104-76-7
Acrylyl chloride structure

Acrylyl chloride

CAS#:814-68-6

~%

2-Ethylhexyl acrylate Structure

2-Ethylhexyl ac...

CAS#:103-11-7
Literature: Tetrahedron, , vol. 48, # 31 p. 6371 - 6384
2-Ethylhexanol structure

2-Ethylhexanol

CAS#:104-76-7
Acrylic acid structure

Acrylic acid

CAS#:79-10-7

~%

2-Ethylhexyl acrylate Structure

2-Ethylhexyl ac...

CAS#:103-11-7

2-ethylhexyl 3-(2-ethylhexoxy)propanoate structure

2-ethylhexyl 3-...

CAS#:38940-91-9
Literature: J. Appl. Chem. USSR (Engl. Transl.), , vol. 64, # 9 p. 1955 - 1959,1811 - 1815

 Customs

HS Code 2916129000
Summary 2916129000 other esters of acrylic acid VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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 Synonyms

ETHOXY-2-ETHYLACRYLATE
2-Ethyl-1-hexyl acrylate
Acrylic Acid 2-Ethylhexyl Ester Monomer
UNII-HR49R9S6XG
2-Propenoic acid, 2-ethylhexyl ester
2-ethylhexyl propenoate
2-ethyl
2-Ethylhexanol acrylate
2-ethyl-hexyl acrylate
MFCD00009495
2-Ethyl hexyl acrylate
acrylic acid, 2-ethylhexyl ester
Octyl Acrylate Monomer
ethylhexyl acrylate
2-Ethylhexyl acrylate (2-EHA)
Mono(2-ethylhexyl) acrylate
2-ethylhexyl prop-2-enoate
2-ETHYLEXYL ACRYLATE
EINECS 203-080-7
Acrylic Acid Octyl Ester Monomer
OCTYL ACRYLATE
2-Propenoic acid 2-ethylhexyl ester
acrylic acid 2-ethylhexyl ester
2-EHA
ETHYL-2-HEXYLACRYLATE
1-Hexanol, 2-ethyl-, acrylate
2-ethvlhexvlacrvlate
O-2-ethylhexyl acrylate
2-ethylheksyl acrylate
2-Ethylhexyl Acrylate Monomer
EHA
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Chemsrc provides 2-Ethylhexyl acrylate(CAS#:103-11-7) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Articles of 2-Ethylhexyl acrylate are included as well.>> amp version: 2-Ethylhexyl acrylate

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