Carbamodithioic acid,N-cyano-, methyl ester, potassium salt (1:1)

Modify Date: 2024-01-03 15:28:49

Carbamodithioic acid,N-cyano-, methyl ester, potassium salt (1:1) Structure
Carbamodithioic acid,N-cyano-, methyl ester, potassium salt (1:1) structure
Common Name Carbamodithioic acid,N-cyano-, methyl ester, potassium salt (1:1)
CAS Number 10191-61-4 Molecular Weight 170.29800
Density 1.332g/cm3 Boiling Point 196.3ºC at 760mmHg
Molecular Formula C3H3KN2S2 Melting Point 210-212ºC
MSDS N/A Flash Point 72.5ºC

 Names

Name potassium,N-cyano-1-methylsulfanylmethanimidothioate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.332g/cm3
Boiling Point 196.3ºC at 760mmHg
Melting Point 210-212ºC
Molecular Formula C3H3KN2S2
Molecular Weight 170.29800
Flash Point 72.5ºC
Exact Mass 169.93700
PSA 86.75000
LogP 1.38398
Appearance of Characters Crystalline Powder | Off-white to beige
Vapour Pressure 0.401mmHg at 25°C
Index of Refraction 1.617

 MSDS

Name: Cyanimidodithiocarbonic Acid Monomethyl Ester Monopotassium Salt, 98% Material Safety Data Sheet
Synonym: None.
CAS: 10191-61-4
Section 1 - Chemical Product MSDS Name: Cyanimidodithiocarbonic Acid Monomethyl Ester Monopotassium Salt, 98% Material Safety Data Sheet
Synonym: None.
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10191-61-4 Cyanimidodithiocarbonic Acid Monomethy 98% unlisted
+++++
Hazard Symbols: XN
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful in contact with skin and if swallowed.The toxicological properties of this material have not been fully investigated. Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.
SECTION 4 - FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:


SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.
SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 10191-61-4: Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: Not available.
Odor: Weak
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble in water
Specific Gravity/Density:
Molecular Formula: C3H3KN2S2
Molecular Weight: 170.28
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 10191-61-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Cyanimidodithiocarbonic Acid Monomethyl Ester Monopotassium Salt - Not listed by ACGIH, IARC, or NTP.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material.
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 21/22 Harmful in contact with skin and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with plenty of water. S 36/37 Wear suitable protective clothing and gloves. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 10191-61-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 10191-61-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 10191-61-4 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 2/19/1999 Revision #2 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn: Harmful;
Risk Phrases R36/37/38
Safety Phrases 36/37/39-26
HS Code 2930909090

 Synthetic Route

~74%

Carbamodithioic acid,N-cyano-, methyl ester, potassium salt (1:1) Structure

Carbamodithioic...

CAS#:10191-61-4

Literature: PFIZER INC.; BUNNAGE, Mark, Edward; COOK, Andrew, Simon; CUI, Jingrong, Jean; DACK, Kevin, Neil; DEAL, Judith, Gail; GU, Danlin; HE, Mingying; JOHNSON, Patrick, Stephen; JOHNSON, Ted, William; LE, Phuong, Thi, Quy; PALMER, Cynthia, Louise; SHEN, Hong Patent: WO2011/138751 A2, 2011 ; Location in patent: Page/Page column 120-121 ;

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

potassium methyl N-cyanodithioimidocarbonate
N-cyano-S-methyldithiocarbamic acid potassium salt
Cyanimidodithiocarbonic acid monomethyl ester monopotassium salt
Potassium S-methyl-cyanimidodithiocarbonate
cyanimidodithiocarbonic acid monomethyl ester monopotassium salt
potassium methyl cyanimidodithiocarbonate
Cyanimidodithiokohlensaeure-methylester-kaliumsalz
Kalium-methyl-cyanimido-dithiocarbonat
potassium S-methyl N-cyanocarbamodithioate
potassium {[(methylthio)(sulphido)methylene]amino}(nitrilo)methane
KAZAbUpYDAAA@RWXEEBjfpSP
N-Cyano-Carbamodithioic Acid Methyl Ester Potassium Salt
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