90064-46-3

90064-46-3 structure
90064-46-3 structure
  • Name: 1-Chloro-4-iodo-2,5-dimethoxybenzene
  • Chemical Name: 1-Chloro-4-iodo-2,5-dimethoxybenzene
  • CAS Number: 90064-46-3
  • Molecular Formula: C8H8ClIO2
  • Molecular Weight: 298.50500
  • Create Date: 2018-12-29 17:29:21
  • Modify Date: 2024-01-05 17:53:57

Name 1-Chloro-4-iodo-2,5-dimethoxybenzene
Synonyms 1-Chlor-4-jod-2,5-dimethoxy-benzol
1-chloro-4-iodo-2,5-dimethoxy-benzene
1-chloro-4-iodo-2,5-dimetoxybenzene
4-Chloro-2,5-dimethoxyiodobenzene
HMS550H22
Density 1.74g/cm3
Boiling Point 324.8ºC at 760mmHg
Melting Point 115-116ºC
Molecular Formula C8H8ClIO2
Molecular Weight 298.50500
Flash Point 150.2ºC
Exact Mass 297.92600
PSA 18.46000
LogP 2.96180
Index of Refraction 1.584
Name: 1-Chloro-4-iodo-2 5-dimethoxybenzene 97% Material Safety Data Sheet
Synonym:
CAS: 90064-46-3
Section 1 - Chemical Product MSDS Name:1-Chloro-4-iodo-2 5-dimethoxybenzene 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
90064-46-3 1-Chloro-4-iodo-2,5-dimethoxybenzene 97% unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 90064-46-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: cream
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 115 - 116 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H8ClIO2
Molecular Weight: 299

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen iodide, iodine, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 90064-46-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Chloro-4-iodo-2,5-dimethoxybenzene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 90064-46-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 90064-46-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 90064-46-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38

~58%

90064-46-3 structure

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Literature: Wariishi, Koji; Morishima, Sin-Ichi; Inagaki, Yoshio Organic Process Research and Development, 2003 , vol. 7, # 1 p. 98 - 100

~23%

90064-46-3 structure

90064-46-3

Literature: Sargent, Thornton; Shulgin, Alexander T.; Mathis, Chester A. Journal of Medicinal Chemistry, 1984 , vol. 27, # 8 p. 1071 - 1077

~53%

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90064-46-3

Literature: Huenig, Siegfried; Bau, Robert; Kemmer, Martina; Meixner, Hubert; Metzenthin, Tobias; et al. European Journal of Organic Chemistry, 1998 , # 2 p. 335 - 348

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90064-46-3 structure

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Literature: Posternak et al. Helvetica Chimica Acta, 1948 , vol. 31, p. 525,535

~%

90064-46-3 structure

90064-46-3

Literature: Posternak et al. Helvetica Chimica Acta, 1948 , vol. 31, p. 525,535

~%

90064-46-3 structure

90064-46-3

Literature: Posternak et al. Helvetica Chimica Acta, 1948 , vol. 31, p. 525,535

~%

90064-46-3 structure

90064-46-3

Literature: Kauffmann; Fritz Chemische Berichte, 1908 , vol. 41, p. 4424