Name | 1-Chloro-4-iodo-2,5-dimethoxybenzene |
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Synonyms |
1-Chlor-4-jod-2,5-dimethoxy-benzol
1-chloro-4-iodo-2,5-dimethoxy-benzene 1-chloro-4-iodo-2,5-dimetoxybenzene 4-Chloro-2,5-dimethoxyiodobenzene HMS550H22 |
Density | 1.74g/cm3 |
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Boiling Point | 324.8ºC at 760mmHg |
Melting Point | 115-116ºC |
Molecular Formula | C8H8ClIO2 |
Molecular Weight | 298.50500 |
Flash Point | 150.2ºC |
Exact Mass | 297.92600 |
PSA | 18.46000 |
LogP | 2.96180 |
Index of Refraction | 1.584 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Light sensitive. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 90064-46-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: cream Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 115 - 116 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H8ClIO2 Molecular Weight: 299 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, light. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen iodide, iodine, acrid smoke and fumes. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 90064-46-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 1-Chloro-4-iodo-2,5-dimethoxybenzene - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 90064-46-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 90064-46-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 90064-46-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi: Irritant; |
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Risk Phrases | R36/37/38 |
~58% 90064-46-3 |
Literature: Wariishi, Koji; Morishima, Sin-Ichi; Inagaki, Yoshio Organic Process Research and Development, 2003 , vol. 7, # 1 p. 98 - 100 |
~23% 90064-46-3 |
Literature: Sargent, Thornton; Shulgin, Alexander T.; Mathis, Chester A. Journal of Medicinal Chemistry, 1984 , vol. 27, # 8 p. 1071 - 1077 |
~53% 90064-46-3 |
Literature: Huenig, Siegfried; Bau, Robert; Kemmer, Martina; Meixner, Hubert; Metzenthin, Tobias; et al. European Journal of Organic Chemistry, 1998 , # 2 p. 335 - 348 |
~% 90064-46-3 |
Literature: Posternak et al. Helvetica Chimica Acta, 1948 , vol. 31, p. 525,535 |
~% 90064-46-3 |
Literature: Posternak et al. Helvetica Chimica Acta, 1948 , vol. 31, p. 525,535 |
~% 90064-46-3 |
Literature: Posternak et al. Helvetica Chimica Acta, 1948 , vol. 31, p. 525,535 |
~% 90064-46-3 |
Literature: Kauffmann; Fritz Chemische Berichte, 1908 , vol. 41, p. 4424 |
Precursor 6 | |
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DownStream 3 | |