1154-59-2

1154-59-2 structure
1154-59-2 structure
  • Name: 3,3',4',5-tetrachlorosalicylanilide
  • Chemical Name: 3,3',4',5-tetrachlorosalicylanilide
  • CAS Number: 1154-59-2
  • Molecular Formula: C13H7Cl4NO2
  • Molecular Weight: 351.01200
  • Create Date: 2018-08-22 12:12:17
  • Modify Date: 2024-01-02 18:40:16

Name 3,3',4',5-tetrachlorosalicylanilide
Synonyms Caswell No. 833
SALICYLANILIDE,3,3',4',5-TETRACHLORO
3,3',4',5-Tetrachlorosalicylanilide
Irgasan BS-200
3,5-Dichlorosalicyl 3,4-dichloroanilide
Benzamide,3,5-dichloro-N-(3,4-dichlorophenyl)-2-hydroxy
EINECS 214-576-8
TCSA
3,5-dichloro-N-(3,4-dichloro-phenyl)-2-hydroxy-benzamide
Tetrachlorosalicylanilide
3,5,3',4'-tetrachlorosalicylanilide
3,5-dichloro-N-(3,4-dichlorophenyl)-2-hydroxybenzamide
3,3′,4′,5-Tetrachlorosalicylanilide
Density 1.636 g/cm3
Boiling Point 408.1ºC at 760 mmHg
Melting Point 162ºC
Molecular Formula C13H7Cl4NO2
Molecular Weight 351.01200
Flash Point 200.6ºC
Exact Mass 348.92300
PSA 49.33000
LogP 5.33110
Vapour Pressure 3.03E-07mmHg at 25°C
Index of Refraction 1.693
Name: 3 3 4 5-Tetrachlorosalicylanilide 99% (UV-Vis) Material Safety Data Sheet
Synonym: Benzamide,3,5-Dichloro-N-(3,4-Dichlorophenyl)-2-Hydroxy
CAS: 1154-59-2
Section 1 - Chemical Product MSDS Name:3 3 4 5-Tetrachlorosalicylanilide 99% (UV-Vis) Material Safety Data Sheet
Synonym:Benzamide,3,5-Dichloro-N-(3,4-Dichlorophenyl)-2-Hydroxy

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1154-59-2 Benzamide,3,5-dichloro-n-(3,4-dichloro 99 214-576-8
Hazard Symbols: XN
Risk Phrases: 22

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful if swallowed.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1154-59-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 162 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C13H7Cl4NO2
Molecular Weight: 351.01

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide, oxides of chlorine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1154-59-2: VN8900000 LD50/LC50:
CAS# 1154-59-2: Oral, rat: LD50 = 243 mg/kg.
Carcinogenicity:
Benzamide,3,5-dichloro-n-(3,4-dichlorophenyl)-2-hydroxy- - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1154-59-2: No information available.
Canada
CAS# 1154-59-2 is listed on Canada's DSL List.
CAS# 1154-59-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1154-59-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VN8900000
CHEMICAL NAME :
Salicylanilide, 3,3',4',5-tetrachloro-
CAS REGISTRY NUMBER :
1154-59-2
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C13-H7-Cl4-N-O2
MOLECULAR WEIGHT :
351.01
WISWESSER LINE NOTATION :
GR BG DMVR BQ CG EG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
JSCCA5 Journal of the Society of Cosmetic Chemists. (Soc. of Cosmetic Chemists, 1995 Broadway, Suite 1701, New York, NY 10023) V.1- 1947- Volume(issue)/page/year: 25,113,1974
TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - guinea pig
REFERENCE :
JSCCA5 Journal of the Society of Cosmetic Chemists. (Soc. of Cosmetic Chemists, 1995 Broadway, Suite 1701, New York, NY 10023) V.1- 1947- Volume(issue)/page/year: 25,113,1974 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
243 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCOC** Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. (Topeka, KS) Volume(issue)/page/year: -,618,1966
Hazard Codes Xn: Harmful;
Risk Phrases R22
HS Code 2924299090
Precursor  2

DownStream  0

HS Code 2924299090
Summary 2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%