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6282-98-0

6282-98-0 structure
6282-98-0 structure

Name 2-methyl-N,N-di(propan-2-yl)propanamide
Synonyms N,N-diisopropyl-2-methylpropionamide
N,N-Diisopropyl-2-methylpropanamide
MFCD00800590
N,N-Diisopropylisobutyramide
diisopropylisobutyramide
N,N-Diisopropyl-isobutyramid
Density 0.86g/cm3
Boiling Point 215.1ºC at 760 mmHg
Molecular Formula C10H21NO
Molecular Weight 171.28000
Flash Point 75.9ºC
Exact Mass 171.16200
PSA 20.31000
LogP 2.28780
Index of Refraction 1.435
Name: N N-Diisopropylisobutyramide Material Safety Data Sheet
Synonym: N,N-Diisopropyl-2-Methylpropionamide; 2-Methyl-N,N-Bis(1-Methylethyl)propanamide
CAS: 6282-98-0
Section 1 - Chemical Product MSDS Name:N N-Diisopropylisobutyramide Material Safety Data Sheet
Synonym:N,N-Diisopropyl-2-Methylpropionamide; 2-Methyl-N,N-Bis(1-Methylethyl)propanamide

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6282-98-0 N,N-Diisopropylisobutyramide ca 100 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store at around 20C.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6282-98-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in most organic solvents
Specific Gravity/Density:
Molecular Formula: C10H21NO
Molecular Weight: 171.28

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 6282-98-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N,N-Diisopropylisobutyramide - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 6282-98-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6282-98-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6282-98-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Safety Phrases S24/25
HS Code 2924199090

~0%

6282-98-0 structure

6282-98-0

Literature: Munyemana, Francois; Frisque-Hesbain, Anne-Marie; Devos, Alain; Ghosez, Leon Tetrahedron Letters, 1989 , vol. 30, # 23 p. 3077 - 3080

~0%

6282-98-0 structure

6282-98-0

Literature: Munyemana, Francois; Frisque-Hesbain, Anne-Marie; Devos, Alain; Ghosez, Leon Tetrahedron Letters, 1989 , vol. 30, # 23 p. 3077 - 3080

~0%

6282-98-0 structure

6282-98-0

Literature: Munyemana, Francois; Frisque-Hesbain, Anne-Marie; Devos, Alain; Ghosez, Leon Tetrahedron Letters, 1989 , vol. 30, # 23 p. 3077 - 3080

~0%

6282-98-0 structure

6282-98-0

Literature: Munyemana, Francois; Frisque-Hesbain, Anne-Marie; Devos, Alain; Ghosez, Leon Tetrahedron Letters, 1989 , vol. 30, # 23 p. 3077 - 3080

~96%

6282-98-0 structure

6282-98-0

Literature: Ghosez, Leon; George-Koch, Isabelle; Patiny, Luc; Houtekie, Marc; Bovy, Philippe; Nshimyumukiza, Prosper; Phan, Thao Tetrahedron, 1998 , vol. 54, # 31 p. 9207 - 9222

~78%

6282-98-0 structure

6282-98-0

Literature: Keinan, Ehud; Perez, Daniel Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2576 - 2580

~%

6282-98-0 structure

6282-98-0

Literature: Kotani, Shunsuke; Osakama, Kazuki; Sugiura, Masaharu; Nakajima, Makoto Organic Letters, 2011 , vol. 13, # 15 p. 3968 - 3971

~%

6282-98-0 structure

6282-98-0

Literature: Cho, Bong Rae; Kim, Yong Kwan; Yoon, Choon-Ock Maing Journal of the American Chemical Society, 1997 , vol. 119, # 4 p. 691 - 697

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6282-98-0 structure

6282-98-0

Detail
Literature: Ernst, Beat.; Winkler, Tammo. Tetrahedron Letters, 1989 , vol. 30, # 23 p. 3081 - 3084
HS Code 2924199090
Summary 2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%