5597-27-3
5597-27-3 structure
- Name: Bicyclo[2.2.1]heptan-2-one,3-methylene-
- Chemical Name: 3-Methylene-2-norbornanone
- CAS Number: 5597-27-3
- Molecular Formula: C8H10O
- Molecular Weight: 122.16400
- Catalog: Chemical reagent Organic reagent Bicyclic compound
- Create Date: 2018-10-04 11:04:24
- Modify Date: 2025-09-14 21:07:21
| Name | 3-Methylene-2-norbornanone |
|---|---|
| Synonyms |
2-methylidenebicyclo[2.2.1]heptan-3-one
MFCD00151643 EINECS 227-009-4 |
| Density | 0.997 g/mL at 25ºC(lit.) |
|---|---|
| Boiling Point | 69-71ºC11 mm Hg(lit.) |
| Melting Point | 69-71ºC |
| Molecular Formula | C8H10O |
| Molecular Weight | 122.16400 |
| Flash Point | 131 °F |
| Exact Mass | 122.07300 |
| PSA | 17.07000 |
| LogP | 1.54160 |
| Index of Refraction | n20/D 1.493(lit.) |
| Symbol |
GHS02 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H226 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Risk Phrases | R10 |
| Safety Phrases | S16 |
| RIDADR | UN 1224 3/PG 3 |
| WGK Germany | 3 |
| Packaging Group | III |
| Hazard Class | 3.2 |
| HS Code | 2914299000 |
|
~85%
5597-27-3 |
| Literature: Hon, Yung-Son; Hsu, Tzyy-Rong; Chen, Chun-Yan; Lin, Yi-Hui; Chang, Fong-Jong; Hsieh, Cheng-Han; Szu, Ping-Hui Tetrahedron, 2003 , vol. 59, # 9 p. 1509 - 1520 |
|
~45%
5597-27-3 |
| Literature: Bowman, W. Russell; Brown, David S.; Burns, Catherine A.; Marples, Brian A.; Zaidi, Naveed A. Tetrahedron, 1992 , vol. 48, # 33 p. 6883 - 6896 |
|
~%
5597-27-3 |
| Literature: Tetrahedron, , vol. 59, # 9 p. 1509 - 1520 |
|
~%
5597-27-3 |
| Literature: Journal of Organic Chemistry, , vol. 32, p. 765 - 771 |
|
~%
5597-27-3 |
| Literature: Journal of Organic Chemistry, , vol. 32, p. 765 - 771 |
|
~%
5597-27-3 |
| Literature: Chemische Berichte, , vol. 89, p. 2198,2206 |
|
~%
5597-27-3 |
| Literature: EP1352890 A1, ; Page/Page column 4 ; |
| Precursor 6 | |
|---|---|
| DownStream 2 | |
![spiro[bicyclo[2.2.1]heptane-3,1'-cyclopropane]-2-one structure](https://image.chemsrc.com/caspic/403/16133-64-5.png)
![2-(2,2-dimethylpropyl)bicyclo[2.2.1]heptan-3-one structure](https://image.chemsrc.com/caspic/279/93175-57-6.png)
| HS Code | 2914299000 |
|---|---|
| Summary | 2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0% |