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814-68-6

814-68-6 structure
814-68-6 structure

Name Acrylyl chloride
Synonyms 2-Propenoyl chloride
prop-2-enoyl chloride
Prop-2-enoylchlorid
MFCD00000731
PROPENOYL CHLORIDE
EINECS 212-399-0
Acryloyl chloride
Density 1.1±0.1 g/cm3
Boiling Point 75.5±0.0 °C at 760 mmHg
Melting Point 72-76ºC
Molecular Formula C3H3ClO
Molecular Weight 90.508
Flash Point 16.1±0.0 °C
Exact Mass 89.987244
PSA 17.07000
LogP 1.06
Vapour density >1 (vs air)
Vapour Pressure 104.8±0.1 mmHg at 25°C
Index of Refraction 1.417
Stability Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AT7350000
CHEMICAL NAME :
Acryloyl chloride
CAS REGISTRY NUMBER :
814-68-6
BEILSTEIN REFERENCE NO. :
0635744
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C3-H3-Cl-O
MOLECULAR WEIGHT :
90.51
WISWESSER LINE NOTATION :
GV1U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
25 ppm/4H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - iritis Behavioral - ataxia Lungs, Thorax, or Respiration - emphysema
REFERENCE :
BJIMAG British Journal of Industrial Medicine. (British Medical Journal, Box 560B, Kennebunkport, ME 04046) V.1- 1944- Volume(issue)/page/year: 27,1,1970
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
92 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,17,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03367 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.3 mg/m3;Skin JAN 1993
Symbol GHS02 GHS05 GHS06
GHS02, GHS05, GHS06
Signal Word Danger
Hazard Statements H225-H314-H330
Precautionary Statements P210-P260-P280-P284-P305 + P351 + P338-P310
Hazard Codes C:Corrosive
Risk Phrases R11;R34
Safety Phrases S16-S26-S28-S36/37/39-S45-S7/9
RIDADR UN 3383 6.1/PG 1
WGK Germany 3
RTECS AT7350000
Packaging Group II
Hazard Class 3
HS Code 2916190090

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Literature: Opaleva; Dogadina; Ionin Russian Journal of General Chemistry, 1997 , vol. 67, # 2 p. 326 - 327

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Literature: Arumugam, Subramaniam; Verkade, John G. Journal of Organic Chemistry, 1997 , vol. 62, # 14 p. 4827 - 4828

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Literature: Societe Nationale des Poudres et Explosifs Patent: US4297301 A1, 1981 ;

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Literature: Journal of the American Chemical Society, , vol. 70, p. 500 Journal of the American Chemical Society, , vol. 60, p. 1326

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Literature: US2050752 , ; GB333079 ; DE547645 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 18, p. 285

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Literature: US2490386 , ;

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Literature: Journal of Organic Chemistry, , vol. 9, p. 509,510

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Detail
Literature: Journal of Molecular Structure, , vol. 443, # 1-3 p. 163 - 173
HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%