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2937-50-0

2937-50-0 structure
2937-50-0 structure
Name Allyl chloroformate
Synonyms 2-propenylchloroformate
MFCD00000648
Alloc-chloride
Alloc-Cl
Carbonochloridic acid, 2-propen-1-yl ester
allyl chlorocarbonate
ACF
allyl chlorofomate
Chloroformic Acid Allyl Ester
EINECS 220-916-6
allyloxycarbonyl chloride
Allyl carbonochloridate
Allylchloroformate
Density 1.2±0.1 g/cm3
Boiling Point 107.7±9.0 °C at 760 mmHg
Melting Point 106℃
Molecular Formula C4H5ClO2
Molecular Weight 120.534
Flash Point 31.1±0.0 °C
Exact Mass 119.997810
PSA 26.30000
LogP 1.74
Vapour Pressure 26.8±0.2 mmHg at 25°C
Index of Refraction 1.429

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ5775000
CHEMICAL NAME :
Formic acid, chloro-, allyl ester
CAS REGISTRY NUMBER :
2937-50-0
BEILSTEIN REFERENCE NO. :
0773915
LAST UPDATED :
199710
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C4-H5-Cl-O2
MOLECULAR WEIGHT :
120.54
WISWESSER LINE NOTATION :
GVO2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
244 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),51,1984
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
32400 ug/m3
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),51,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
210 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),51,1984
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
23100 ug/m3
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),51,1984 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1230 ug/m3/30D-I
TOXIC EFFECTS :
Cardiac - EKG changes not diagnostic of specified effects Liver - fatty liver degeneration Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),51,1984 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.4 mg/m3;Skin JAN 1993
Symbol GHS02 GHS05 GHS06
GHS02, GHS05, GHS06
Signal Word Danger
Hazard Statements H226-H301-H314-H330
Precautionary Statements P260-P280-P284-P301 + P310-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T+: Very toxic;
Risk Phrases R10
Safety Phrases S26-S28-S36/37/39-S45
RIDADR UN 1722 6.1/PG 1
WGK Germany 3
RTECS LQ5775000
Packaging Group I
Hazard Class 6.1(b)
HS Code 2915900090
75-44-5 structure

75-44-5

107-18-6 structure

107-18-6

~%

2937-50-0 structure

2937-50-0

Literature: Falck-Pedersen, Mette Lene; Benneche, Tore; Undheim, Kjell Acta Chemica Scandinavica, 1993 , vol. 47, # 1 p. 63 - 67
75-44-5 structure

75-44-5

107-18-6 structure

107-18-6

~%

15022-08-9 structure

15022-08-9

2937-50-0 structure

2937-50-0

Literature: Fierz-David; Mueller Journal of the Chemical Society, 1924 , vol. 125, p. 26
HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%
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