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2446-84-6

2446-84-6 structure
2446-84-6 structure

Name methyl (NE)-N-methoxycarbonyliminocarbamate
Synonyms Azodicarbonsaeuredimethylester
Formic acid,azodi-,dimethyl ester
dimethyl diazenedicarboxylate
N,N'-dimethyl-azo-dicarboxylate
azodicarbonic acid dimethyl ester
AZODICARBOXYLIC ACID DIMETHYL ESTER
MeO2CN=NCO2Me
Dimethyl Azodicarboxylate
Density 1.3g/cm3
Boiling Point 206.4ºC at 760mmHg
Melting Point 10°C
Molecular Formula C4H6N2O4
Molecular Weight 146.10100
Flash Point 96.1ºC
Exact Mass 146.03300
PSA 77.32000
LogP 0.97140
Vapour Pressure 0.238mmHg at 25°C
Index of Refraction 1.468
Name: Methyl azodicarboxylate 97% Material Safety Data Sheet
Synonym: Dimethyl diazenedicarboxylat
CAS: 2446-84-6
Section 1 - Chemical Product MSDS Name:Methyl azodicarboxylate 97% Material Safety Data Sheet
Synonym:Dimethyl diazenedicarboxylat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
2446-84-6 Methyl azodicarboxylate 97 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 2446-84-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Clear liquid
Color: clear brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C4H6N2O4
Molecular Weight: 146.10

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 2446-84-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl azodicarboxylate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 2446-84-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2446-84-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2446-84-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Risk Phrases 11-36/37/38
Safety Phrases S9;S16;S33
RIDADR UN 1993
HS Code 2927000090

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2446-84-6 structure

2446-84-6

Literature: Kalinin, A. V.; Apasov, E. T.; Ioffe, S. L.; Tartakovskii, V. A. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 5.1 p. 988 - 995 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 5 p. 1108 - 1114

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2446-84-6 structure

2446-84-6

Literature: Shinada, Tetsuro; Hamada, Makoto; Miyoshi, Kota; Higashino, Masato; Umezawa, Taiki; Ohfune, Yasufumi Synlett, 2010 , # 14 art. no. U03510ST, p. 2141 - 2145

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2446-84-6 structure

2446-84-6

Literature: Diels; Paquin Chemische Berichte, 1913 , vol. 46, p. 2012 Full Text Show Details Diels; Fritzsche Chemische Berichte, 1911 , vol. 44, p. 3022

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2446-84-6 structure

2446-84-6

Detail
Literature: Teles, Joaquim Henrique; Maier, Guenther Chemische Berichte, 1989 , vol. 122, p. 745 - 748

~%

2446-84-6 structure

2446-84-6

Literature: Diels; Paquin Chemische Berichte, 1913 , vol. 46, p. 2012 Full Text Show Details Diels; Fritzsche Chemische Berichte, 1911 , vol. 44, p. 3022

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Detail
Literature: Teles, Joaquim Henrique; Maier, Guenther Chemische Berichte, 1989 , vol. 122, p. 745 - 748
HS Code 2927000090
Summary 2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%