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17501-44-9

17501-44-9 structure
17501-44-9 structure
Name Zirconium(IV) Acetylacetonate
Synonyms 2,4-Pentanedione, zirconium salt (4:1)
Zirconium(IV) 2,4-pentanedionate
Tetrakis(2,4-pentanedionato)zirconium
2,4-Pentanedione zirconium(IV) derivative
Zirconium(IV) acetylacetonate
Tetrakis(2,4-pentanedionato)zirconium(IV)
EINECS 241-510-5
MFCD00000036
2,4-Pentanedione - zirconium (4:1)
Acetylacetone Zirconium(IV) Salt
Boiling Point 187.6ºC at 760 mmHg
Melting Point 171-173ºC
Molecular Formula C20H32O8Zr
Molecular Weight 491.687
Flash Point 71.9ºC
Exact Mass 490.114410
PSA 136.56000
LogP 2.21800
Storage condition Store below +30°C.
Water Solubility 14g/l

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZH9280000
CHEMICAL NAME :
Zirconium, tetrakis(2,4-pentanedionato-O,O')-
CAS REGISTRY NUMBER :
17501-44-9
LAST UPDATED :
199712
DATA ITEMS CITED :
23
MOLECULAR FORMULA :
C20-H28-O8-Zr
MOLECULAR WEIGHT :
487.70
WISWESSER LINE NOTATION :
1V1V1 2 &-ZR-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
316 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD441-640
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Ocular
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Sense Organs and Special Senses (Eye) - corneal damage
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD441-640 *** REVIEWS *** ACGIH TLV-TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,285,1971 OSHA PEL (Gen Indu):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-DENMARK:TWA 5 mg(Zr)/m3 JAN 1993 OEL-FINLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-GERMANY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-HUNGARY:STEL 5 mg(Zr)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 5 mg(Zr)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 5 mg(Zr)/m3 JAN 1993 OEL-SWITZERLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-TURKEY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV
Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302 + H312 + H332-H315-H319-H335
Precautionary Statements P261-P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn
Risk Phrases R22
Safety Phrases S22-S36/37
RIDADR NONH for all modes of transport
WGK Germany 3
RTECS ZH9280000
HS Code 2914509090
7440-67-7 structure

7440-67-7

123-54-6 structure

123-54-6

~87%

17501-44-9 structure

17501-44-9

Literature: Grinberg, Ya. Kh.; Lazarev, V. B.; Zavernyaev, A. Yu.; Shreider, V. A.; Chepik, S. D. Russian Journal of Physical Chemistry, 1986 , vol. 60, # 4 p. 630 - 631 Zhurnal Fizicheskoi Khimii, 1986 , vol. 60, p. 1044
856891-93-5 structure

856891-93-5

123-54-6 structure

123-54-6

~32%

17501-44-9 structure

17501-44-9

671790-74-2 structure

671790-74-2

Literature: Wang, Hong; Chan, Hoi-Shan; Okuda, Jun; Xie, Zuowei Organometallics, 2005 , vol. 24, # 13 p. 3118 - 3124
75763-81-4 structure

75763-81-4

~%

17501-44-9 structure

17501-44-9

Literature: Journal of General Chemistry USSR (English Translation), , vol. 50, p. 1349 - 1352 Zhurnal Obshchei Khimii, , vol. 50, p. 1665 - 1668
10026-11-6 structure

10026-11-6

123-54-6 structure

123-54-6

~%

17501-44-9 structure

17501-44-9

Literature: Soviet Progress in Chemistry (English translation of Ukrainskii Khimicheskii Zhurnal), , vol. 49, # 7 p. 8 - 12
148486-34-4 structure

148486-34-4

123-54-6 structure

123-54-6

~%

17501-44-9 structure

17501-44-9

Literature: Chemical Communications, , # 16 p. 1874 - 1875
24356-01-2 structure

24356-01-2

~99%

17501-44-9 structure

17501-44-9

Literature: Brainina, E. M.; Minacheva, M. Kh. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1984 , vol. 33, p. 655 - 657 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1984 , vol. 33, p. 705 - 707
HS Code 2914509090
Summary HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
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