Heptanal, 2-benzylidene-
Names
[ CAS No. ]:
122-40-7
[ Name ]:
Heptanal, 2-benzylidene-
[Synonym ]:
2-Benzylideneheptanal
Amyl cinnamal
FEMA 2061
Heptanal, 2-(phenylmethylene)-, (2E)-
α-Amylcinnamaldehyde
2-Amyl-3-phenylacrylaldehyde
JASMINAL
Heptanal, 2-benzylidene-
EINECS 204-541-5
(2E)-2-(phenylmethylidene)heptanal
Cinnamaldehyde, α-pentyl-
Heptanal, 2-(phenylmethylene)
Heptanal, 2-(phenylmethylene)-
α-Pentylcinnamaldehyde
Jasminealde-hyde
α-Amylcinnamic aldehyde
Flomine
2-(Phenylmethylene)heptanal
2-Amyl-3-phenyl-2-propenal
Jasminaldehyde
MFCD00006988
2-(Phenylmethylene)-heptanal
(2E)-2-Benzylideneheptanal
Heptanal, 2- (phenylmethylene)-
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
288.5±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C14H18O
[ Molecular Weight ]:
202.292
[ Flash Point ]:
131.1±14.6 °C
[ Exact Mass ]:
202.135757
[ PSA ]:
17.07000
[ LogP ]:
4.80
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.534
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- GD6825000
- CHEMICAL NAME :
- Cinnamaldehyde, alpha-pentyl-
- CAS REGISTRY NUMBER :
- 122-40-7
- BEILSTEIN REFERENCE NO. :
- 0511292
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 8
- MOLECULAR FORMULA :
- C14-H18-O
- MOLECULAR WEIGHT :
- 202.32
- WISWESSER LINE NOTATION :
- VHY5&U1R
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- CTOIDG Cosmetics and Toiletries. (Allured Pub. Corp., POB 318, Wheaton, IL 60189) V.91- 1976- Volume(issue)/page/year: 94(8),41,1979
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - guinea pig
- REFERENCE :
- ADVEA4 Acta Dermato-Venereologica. (Almqvist & Wiksell, POB 45150, S-10430 Stockholm, Sweden) V.1- 1920- Volume(issue)/page/year: 58,121,1978
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - guinea pig
- REFERENCE :
- CTOIDG Cosmetics and Toiletries. (Allured Pub. Corp., POB 318, Wheaton, IL 60189) V.91- 1976- Volume(issue)/page/year: 94(8),41,1979 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3730 mg/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - somnolence (general depressed activity)
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1835 No. of Facilities: 6963 (estimated) No. of Industries: 22 No. of Occupations: 31 No. of Employees: 79408 (estimated) No. of Female Employees: 47945 (estimated)
Safety Information
[ Symbol ]:
GHS07, GHS09
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H317-H411
[ Precautionary Statements ]:
P273-P280
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
UN 3082 9 / PGIII
[ WGK Germany ]:
2
[ RTECS ]:
GD6825000
[ HS Code ]:
2912299000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2912299000
[ Summary ]:
2912299000. other cyclic aldehydes without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
Articles
Contact Dermatitis 38(1) , 29-35, (1998)
Deodorants are one of the most frequently used types of cosmetics and side-effects from them are common. Recent studies relate perfume allergy to this type of product. 73 deodorants were analyzed by g...
Natural ingredients based cosmetics. Content of selected fragrance sensitizers.Contact Dermatitis 34(6) , 423-6, (1996)
In the present study, we have investigated 42 cosmetic products based on natural ingredients for content of 11 fragrance substances: geraniol, hydroxycitronellal, eugenol, isoeugenol, cinnamic aldehyd...
Protein binding and metabolism influence the relative skin sensitization potential of cinnamic compounds.Chem. Res. Toxicol. 17(3) , 301-10, (2004)
Skin protein modification (haptenation) is thought to be a key step in the manifestation of sensitization to low molecular mass chemicals (<500 g/mol). For sensitizing chemicals that are not protein r...