(S)-(+)-Benzyl glycidyl ether
Names
[ CAS No. ]:
16495-13-9
[ Name ]:
(S)-(+)-Benzyl glycidyl ether
[Synonym ]:
(2S)-2-[(Benzyloxy)methyl]oxirane
(S)-1-(Benzyloxy)-2,3-epoxypropane
Benzyl S-(+)-glycidyl ether
(S)-(+)-2-(Benzyloxymethyl)oxirane
MFCD00054428
Benzyl (S)-(+)-Glycidyl Ether
(S)-(+)-1-Benzyloxy-2,3-epoxypropane
(2S)-2-(phenylmethoxymethyl)oxirane
(S)-2-((Benzyloxy)methyl)oxirane
(2R)-2-[(Benzyloxy)methyl]oxirane
(R)-1-(Benzyloxy)-2,3-epoxypropane
(r)-benzyloxymethyl-oxirane
( S)-(+)-2-(benzyloxymethyl)-oxirane
Chemical & Physical Properties
[ Density]:
1.1±0.1 g/cm3
[ Boiling Point ]:
252.7±15.0 °C at 760 mmHg
[ Molecular Formula ]:
C10H12O2
[ Molecular Weight ]:
164.201
[ Flash Point ]:
100.9±19.9 °C
[ Exact Mass ]:
164.083725
[ PSA ]:
21.76000
[ LogP ]:
2.04
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.535
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TX2860020
- CHEMICAL NAME :
- Propane, 1-(benzyloxy)-2,3-epoxy-, (R)-
- CAS REGISTRY NUMBER :
- 16495-13-9
- LAST UPDATED :
- 199410
- DATA ITEMS CITED :
- 4
- MOLECULAR FORMULA :
- C10-H12-O2
- MOLECULAR WEIGHT :
- 164.22
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Mutation test systems - not otherwise specified
- TYPE OF TEST :
- Cytogenetic analysis
MUTATION DATA
- TEST SYSTEM :
- Rodent - mouse
- DOSE/DURATION :
- 100 mg/kg
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ RTECS ]:
TX2860030
[ HS Code ]:
2910900090
Customs
[ HS Code ]: 2910900090
[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
Articles
J. Basic Microbiol. 52(4) , 383-9, (2012)
The incubation of whole Bacillus alcalophilus cells grown on a mineral supplemented medium (MSM) containing 1% (w/v) sucrose as carbon source, 1.2% (w/v) tryptone as nitrogen source at pH 6.5 and temp...
Metal-mediated cyclization of aryl and benzyl glycidyl ethers: a complete scenario.J. Am. Chem. Soc. 130(50) , 16838-9, (2008)
Enantiomerically pure aryl and benzyl glycidyl ethers undergo stereospecific cyclizations leading to 3-chromanols or to tetrahydrobenzo[c]oxepin-4-ols under mild conditions in the presence of a cataly...
Enantioselective total synthesis of (+)-gigantecin: exploiting the asymmetric glycolate aldol reaction.J. Am. Chem. Soc. 126(40) , 12790-1, (2004)
The enantioselective synthesis of the potent, selective, cytotoxic, annonaceous acetogenin, (+)-gigantecin, has been completed. An asymmetric glycolate aldol serves to establish the stereocenters at C...