SnAP Pip Reagent

[ Density]:
1.108 g/mL

[ Molecular Formula ]:
C₂₀H₄₄N₂O₂Sn

[ Molecular Weight ]:
463.29

[ Appearance of Characters ]:
liquid

[ Index of Refraction ]:
n/D1.4860

[ Storage condition ]:
-20°C

[ Symbol ]:

GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H315-H319-H335-H410

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310-P305 + P351 + P338-P311

[ RIDADR ]:
UN 2788 6.1 / PGIII

SnAP reagents for the transformation of aldehydes into substituted thiomorpholines--an alternative to cross-coupling with saturated heterocycles.

Angew. Chem. Int. Ed. Engl. 52(6) , 1705-8, (2013)

SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes.

Nature Chemistry 6(4) , 310-4, (2014)

Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing. Reliable and predictable synthetic methods for the preparation of these compounds, especially ...

One-step synthesis of saturated spirocyclic N-heterocycles with stannyl amine protocol (SnAP) reagents and ketones.

J. Am. Chem. Soc. 136(51) , 17726-9, (2014)

The combination of cyclic ketones and stannyl amine protocol (SnAP) reagents affords saturated, spirocyclic N-heterocycles under operationally simple reaction conditions. The resulting, N-unprotected ...

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