Acetylvaline
Names
[ CAS No. ]:
96-81-1
[ Name ]:
Acetylvaline
[Synonym ]:
(2S)-2-acetamido-3-methylbutanoic acid
Valine, N-acetyl-, L-
EINECS 202-537-8
MFCD00066066
DL-Valine, N-acetyl-
N-Acetyl-L-valine
L-Valine, N-acetyl-
Ac-Val-OH
Biological Activity
[Description]:
[Related Catalog]:
[Target]
Human Endogenous Metabolite
Chemical & Physical Properties
[ Density]:
1.1±0.1 g/cm3
[ Boiling Point ]:
362.2±25.0 °C at 760 mmHg
[ Melting Point ]:
165 °C
[ Molecular Formula ]:
C7H13NO3
[ Molecular Weight ]:
159.183
[ Flash Point ]:
172.8±23.2 °C
[ Exact Mass ]:
159.089539
[ PSA ]:
66.40000
[ LogP ]:
-0.19
[ Vapour Pressure ]:
0.0±1.7 mmHg at 25°C
[ Index of Refraction ]:
1.457
[ Storage condition ]:
−20°C
MSDS
Safety Information
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36
[ Safety Phrases ]:
26-36/37
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2924199090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2924199090
[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
J. Am. Chem. Soc. 137(43) , 13894-901, (2015)
Acylated amino acid ligands enabled ruthenium(II)-catalyzed C-H functionalizations with excellent levels of meta-selectivity. The outstanding catalytic activity of the ruthenium(II) complexes derived ...
Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism.J. Am. Chem. Soc. 132(40) , 14137-51, (2010)
Initial rate studies have revealed dramatic acceleration in aerobic Pd(II)-catalyzed C-H olefination reactions of phenylacetic acids when mono-N-protected amino acids are used as ligands. In light of ...