1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

Names

[ Name ]:
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

[Synonym ]:
1,1'-Bis(di-tert-butylphosphino)ferrocenepalladiumdichloride
1,1'-Bis(di-tert-butylphosphino)ferrocene - dichloropalladium (1:1)
MFCD08064219
1,1'-Bis[bis(2-methyl-2-propanyl)phosphino]ferrocene - dichloropalladium (1:1)

Chemical & Physical Properties

[ Melting Point ]:
203-208ºC

[ Molecular Formula ]:
C₂₆H₄₄Cl₂FeP₂Pd

[ Molecular Weight ]:
651.746

[ Exact Mass ]:
650.067932

[ PSA ]:
27.18000

[ LogP ]:
9.65990

[ Appearance of Characters ]:
crystal | dark purple

[ Storage condition ]:
?20°C

[ Water Solubility ]:
Soluble in dichloromethane and chloroform. Partially soluble in acetone, alcohols, tertrahydrofuran and dioxane.

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
24/25

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
28439000

Articles

Room-temperature Suzuki-Miyaura couplings in water facilitated by nonionic amphiphiles.

Org. Lett. 10 , 1333, (2008)

Use of a dilute aqueous solution containing a nonionic amphiphile allows efficient Suzuki-Miyaura cross-couplings of arylboronic acids with a wide array of aryl halides and pseudohalides, including st...

Cp2Fe(PR2)2PdCl2 (R = i-Pr, t-Bu) complexes as air-stable catalysts for challenging Suzuki coupling reactions.

Org. Lett. 6 , 3731, (2004)

[reaction: see text] The use of Cp(2)Fe(PR(2))(2)PdCl(2) (R = i-Pr and t-Bu) in Suzuki coupling reactions were illustrated using a high throughput screening approach. The di-tbpfPdCl(2) catalyst was s...

Heck couplings at room temperature in nanometer aqueous micelles.

Org. Lett. 10 , 1329, (2008)

A nonionic amphiphile such as Triton X-100 or the vitamin E-based PTS, both of which form nanomicelles in water, promotes Heck cross-couplings of non-water-soluble partners at ambient temperatures. Th...