2-METHOXY-1-NAPHTHOIC ACID

Names

[ CAS No. ]:
947-62-6

[ Name ]:
2-METHOXY-1-NAPHTHOIC ACID

[Synonym ]:
1-Naphthoic acid,2-methoxy
2-methoxy-1-naphthalenecarboxylic acid
2-Methoxy-[1]naphthoesaeure
2-Methoxynaphthoic acid
2-Methoxy-1-naphthoic acid
2-methoxy-naphthalene-1-carboxylic acid
EINECS 213-429-5
MFCD00021532

Chemical & Physical Properties

[ Density]:
1.263g/cm3

[ Boiling Point ]:
390.2ºC at 760mmHg

[ Melting Point ]:
177-180ºC(lit.)

[ Molecular Formula ]:
C₁₂H₁₀O₃

[ Molecular Weight ]:
202.20600

[ Flash Point ]:
156.5ºC

[ Exact Mass ]:
202.06300

[ PSA ]:
46.53000

[ LogP ]:
2.54660

[ Index of Refraction ]:
1.64

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2918990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

The Reaction of Phenyl 2-Methoxy-1-naphthoate with Grignard Reagents. A New Route to Fluorenones. Fuson RC and Wassmundt FW.

J. Am. Chem. Soc. 78(20) , 5409-5413, (1956)

Enantioselective synthesis of binaphthyls via nucleophilic aromatic substitution on chiral oxazolines. Meyers AI and Lutomski KA.

J. Am. Chem. Soc. 104(3) , 879-881, (1982)

Birch Reduction of 2-Naphthoic and of ortho-Methoxynaphthoic Acids. Eliel EL and Hoover TE.

J. Org. Chem. 24(7) , 938-942, (1959)