4-Chloro-1-oxo-1-phenylbutane

[ Density]:
1.137 g/mL at 25 °C(lit.)

[ Boiling Point ]:
130-133 °C4 mm Hg

[ Melting Point ]:
19-20 °C(lit.)

[ Molecular Formula ]:
C₁₀H₁₁ClO

[ Molecular Weight ]:
182.64700

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
182.05000

[ PSA ]:
17.07000

[ LogP ]:
2.88830

[ Index of Refraction ]:
n20/D 1.544(lit.)

Click to get detail MSDS

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi: Irritant;

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
UN 2927 6.1/PG 1

[ WGK Germany ]:
3

[ HS Code ]:
2914700090

Click to get detail synthetic route

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

J. Org. Chem. 52 , 1863, (1987)

Neighboring group participation by carbonyl oxygen. Pasto DJ and Serve MP.

J. Am. Chem. Soc. 87(7) , 1515-21, (1965)

In situ generation of Mes2Mg as a non-nucleophilic carbon-centred base reagent for the efficient one-pot conversion of ketones to silyl enol ethers.

Org. Biomol. Chem. 6(7) , 1238-43, (2008)

Treatment of commercially available MesMgBr with 1,4-dioxane produces the key Mes(2)Mg reagent in situ which then mediates the deprotonation of ketones to deliver trimethylsilyl enol ethers, at readil...

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