2-CHLORO-N-METHYLANILINE

Names

[ CAS No. ]:
932-32-1

[ Name ]:
2-CHLORO-N-METHYLANILINE

[Synonym ]:
o-chloro-N-methylaniline
2-Cl-N-Me-aniline
2-(Methylamino)chlorobenzene
2-chloro-N-methyl-aniline
(2-chlorophenyl)methylamine
Benzenamine,2-chloro-N-methyl
n1-methyl-2-chloroaniline
N-Methyl-2-chloroaniline
2-chloranyl-N-methyl-aniline
MFCD00045170
2-chloro-N-methylbenzenamine

Chemical & Physical Properties

[ Density]:
1.15 g/mL at 25 °C(lit.)

[ Boiling Point ]:
218 °C(lit.)

[ Melting Point ]:
218 °C (lit.)

[ Molecular Formula ]:
C₇H₈ClN

[ Molecular Weight ]:
141.59800

[ Flash Point ]:
198 °F

[ Exact Mass ]:
141.03500

[ PSA ]:
12.03000

[ LogP ]:
2.45470

[ Index of Refraction ]:
n20/D 1.579(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
2810

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Articles

Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes. Boebel TA and Hartwig JF.

J. Am. Chem. Soc. 130(24) , 7534-7535, (2008)

Amine‐blocked polyisocyanates. I. Synthesis of novel N‐methylaniline‐blocked polyisocyanates and deblocking studies using hot‐stage fourier transform infrared spectroscopy. Sankar G and Nasar AS.

J. Polym. Sci. A Polym. Chem. 45(8) , 1557-1570, (2007)

Molecular and crystal structures of N-methyl-N-nitro-2-chloroaniline. Prezhdo VV, et al.

Crystallogr. Rep. 46(3) , 389-393, (2001)